Fractal Brownian motion and polymers in external fields

被引:6
|
作者
Washington, GE
机构
[1] Chemistry Department, United States Military Academy at West Point, West Point
来源
JOURNAL OF CHEMICAL PHYSICS | 1996年 / 105卷 / 20期
关键词
D O I
10.1063/1.472760
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Polymer behavior in external fields is modeled using fractal Brownian motion. The chain dimensions of polymer chains with and without excluded volume show a contour length dependence of N-v where v = h - 1. Chains with excluded volume have h = 3/5, chains without excluded volume, Gaussian chains have h = 1/2, and for chains in the collapsed state h = 1/3. This nonphysical result points to the distinction between fractals as models of the trajectory or path of a polymer that are self-similar on all length scales and real polymers that possess a lower and upper limit for self-similarity.
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页码:9324 / 9333
页数:10
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