Synthesis and crystallographic studies of 2-(diphenylphosphinothioyl)-2-(3-oxobut-1-en-yl)-ferrocene

被引：0
|
作者：
Bandyopadhyay, Uchchhal [1 ]
Sundararaju, Basker [2 ]
Poli, Rinaldo [1 ]
Manoury, Eric [1 ]
Daran, Jean-Claude [1 ]
机构：
[1] Univ Toulouse, CNRS, LCC Lab Chim Coordinat, UPS,INPT, 205 Route Narbonne, F-31077 Toulouse 4, France
[2] Indian Inst Technol Kanpur, Dept Chem, Kanpur, Uttar Pradesh, India
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2021年 / 77卷
关键词：
crystal structure; organometallic chemistry; 2-(diphenylphosphinothioyl)ferrocene chemistry; aldol/elimination reaction; GRAPH-SET ANALYSIS; PATTERNS;
D O I：
10.1107/S205698902100760X
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
As a follow-up to our research on the chemistry of disubstituted ferrocene derivatives, the synthesis and the structure of the title compound, 2-(diphenylphosphinothioyl)-2-(3-oxobut-1-en-yl)ferrocene, [Fe(C5H5)(C21H18OPS)], are described. The molecule is built up from a ferrocene unit disubstituted by an S-protected diphenylphosphine group and by a methylvinylketone chain. The crystal structure features weak C-H center dot center dot center dot O and C-H center dot center dot center dot S interactions, which build a two-dimensional network. This structure is compared to that of the related disubstituted diphenylphosphino ferrocene.
引用
收藏
页码：853 / +
页数：10
相关论文
共 50 条
  • [31] Chemistry of iminofurans: IX. Synthesis and cyclization of (2Z)-2-{(2Z)-2-[2-(3-R-adamantan-1-yl)-2-oxoethylidene]hydrazinyl}-4-(het)aryl-4-oxobut-2-enoic acids
    N. A. Pulina
    A. S. Kuznetsov
    A. E. Rubtsov
    Russian Journal of Organic Chemistry, 2015, 51 : 967 - 971
  • [32] Synthesis of substituted 2-(2-Oxopyrrolidin-1-yl)acetamides
    Kavina, M. A.
    Sizov, V. V.
    Yakovlev, I. P.
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2017, 53 (06) : 873 - 878
  • [33] Synthesis of substituted 2-(2-oxopyrrolidin-1-yl)acetamides
    M. A. Kavina
    V. V. Sizov
    I. P. Yakovlev
    Russian Journal of Organic Chemistry, 2017, 53 : 873 - 878
  • [34] Synthesis and Photoluminescent Properties of 2-(3-Carboxymethylindazol-1-yl)anilines
    Shetnev, A. A.
    Panova, V. A.
    Kutuzova, P. M.
    Tarasenko, M. V.
    Zhmykhova, M. V.
    Baykov, S. V.
    Filimonov, S. I.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2021, 91 (06) : 985 - 990
  • [35] Synthesis and Photoluminescent Properties of 2-(3-Carboxymethylindazol-1-yl)anilines
    A. A. Shetnev
    V. A. Panova
    P. M. Kutuzova
    M. V. Tarasenko
    M. V. Zhmykhova
    S. V. Baykov
    S. I. Filimonov
    Russian Journal of General Chemistry, 2021, 91 : 985 - 990
  • [36] A NEW APPROACH TO 2-(1-ALKYL-CYCLOHEX-2-EN-1-YL) PHENOLS
    ESSAMKAOUI, M
    MAYRARGUE, J
    VIERFOND, JM
    REYNET, A
    MOSKOWITZ, H
    THAL, C
    SYNTHETIC COMMUNICATIONS, 1992, 22 (18) : 2723 - 2728
  • [37] [2-(Benzotriazol-1-yl)ethyl][2-(benzotriazol-2-yl)-ethyl]amine
    Zhang, Y
    Liao, ZR
    Li, DF
    Meng, XG
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : O3396 - O3397
  • [38] 2-[2-(1H-indol-3-yl)ethyliminiomethyl]-4-nitrophenolate
    Ali, Hapipah M.
    Mustafa, M. I. Mohamed
    Rizal, M. Razali
    Ng, Seik Weng
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O913 - U2590
  • [39] 2-[(E)-2-(3,4-Dichlorobenzylidene)hydrazin-1-yl]quinoxaline
    Noguiera, Thais C. M.
    Pinheiro, Alexandra C.
    De Souza, Marcus V. N.
    Wardell, James L.
    Tiekink, Edward R. T.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : 0125 - +
  • [40] Crystal Structure of (E)-2-(3,3,3-trifluoroprop-1-en-1-yl)aniline
    Kubono, Koji
    Tani, Keita
    Omote, Masaaki
    Ogawa, Futa
    Matsumoto, Taisuke
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2018, 74 : 1448 - +
12345