Crystal Structure of (E)-2-(3,3,3-trifluoroprop-1-en-1-yl)aniline

被引：0
|
作者：
Kubono, Koji [1 ]
Tani, Keita [1 ]
Omote, Masaaki [2 ]
Ogawa, Futa [2 ]
Matsumoto, Taisuke [3 ]
机构：
[1] Osaka Kyoiku Univ, Div Nat Sci, Kashiwara, Osaka 5828582, Japan
[2] Setsunan Univ, Fac Pharmaceut Sci, Hirakata, Osaka 5730101, Japan
[3] Kyushu Univ, Inst Mat Chem & Engn, Kasuga, Fukuoka 8168580, Japan
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2018年 / 74卷
关键词：
crystal structure; 3,3,3-trifluoroprop-1-en; aniline; hydrogen bonding;
D O I：
10.1107/S2056989018012756
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The molecule of the title compound, C9H8F3N, adopts an E configuration with respect to the C=C double bond. The dihedral angle between the benzene ring and the prop-1-enyl group is 25.4 (3)degrees. In the crystal, molecules are linked via pairs of N-H center dot center dot center dot F hydrogen bonds into inversion dimers with an R-2(2)(16) ring motif. The dimers are linked by C-H center dot center dot center dot N hydrogen bonds, forming a ribbon structure along the b-axis direction. The ribbons are linked by N-H center dot center dot center dot pi and C-H center dot center dot center dot pi interactions, generating a three-dimensional network.
引用
收藏
页码：1448 / +
页数：7
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