Synthesis and crystallographic studies of 2-(diphenylphosphinothioyl)-2-(3-oxobut-1-en-yl)-ferrocene

被引：0
|
作者：
Bandyopadhyay, Uchchhal [1 ]
Sundararaju, Basker [2 ]
Poli, Rinaldo [1 ]
Manoury, Eric [1 ]
Daran, Jean-Claude [1 ]
机构：
[1] Univ Toulouse, CNRS, LCC Lab Chim Coordinat, UPS,INPT, 205 Route Narbonne, F-31077 Toulouse 4, France
[2] Indian Inst Technol Kanpur, Dept Chem, Kanpur, Uttar Pradesh, India
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2021年 / 77卷
关键词：
crystal structure; organometallic chemistry; 2-(diphenylphosphinothioyl)ferrocene chemistry; aldol/elimination reaction; GRAPH-SET ANALYSIS; PATTERNS;
D O I：
10.1107/S205698902100760X
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
As a follow-up to our research on the chemistry of disubstituted ferrocene derivatives, the synthesis and the structure of the title compound, 2-(diphenylphosphinothioyl)-2-(3-oxobut-1-en-yl)ferrocene, [Fe(C5H5)(C21H18OPS)], are described. The molecule is built up from a ferrocene unit disubstituted by an S-protected diphenylphosphine group and by a methylvinylketone chain. The crystal structure features weak C-H center dot center dot center dot O and C-H center dot center dot center dot S interactions, which build a two-dimensional network. This structure is compared to that of the related disubstituted diphenylphosphino ferrocene.
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页码：853 / +
页数：10
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