Synthesis and crystallographic studies of 2-(diphenylphosphinothioyl)-2-(3-oxobut-1-en-yl)-ferrocene

被引：0

作者：

Bandyopadhyay, Uchchhal ^{[1
]}

Sundararaju, Basker ^{[2
]}

Poli, Rinaldo ^{[1
]}

Manoury, Eric ^{[1
]}

Daran, Jean-Claude ^{[1
]}

机构：

[1] Univ Toulouse, CNRS, LCC Lab Chim Coordinat, UPS,INPT, 205 Route Narbonne, F-31077 Toulouse 4, France

[2] Indian Inst Technol Kanpur, Dept Chem, Kanpur, Uttar Pradesh, India

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2021年 / 77卷

关键词：

crystal structure; organometallic chemistry; 2-(diphenylphosphinothioyl)ferrocene chemistry; aldol/elimination reaction; GRAPH-SET ANALYSIS; PATTERNS;

D O I：

10.1107/S205698902100760X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

As a follow-up to our research on the chemistry of disubstituted ferrocene derivatives, the synthesis and the structure of the title compound, 2-(diphenylphosphinothioyl)-2-(3-oxobut-1-en-yl)ferrocene, [Fe(C5H5)(C21H18OPS)], are described. The molecule is built up from a ferrocene unit disubstituted by an S-protected diphenylphosphine group and by a methylvinylketone chain. The crystal structure features weak C-H center dot center dot center dot O and C-H center dot center dot center dot S interactions, which build a two-dimensional network. This structure is compared to that of the related disubstituted diphenylphosphino ferrocene.

引用

页码：853 / +

页数：10

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