Mixed-ligand organometallic derivatives of palladium (O), platinum (O) rhodium (1) and iridium (1) with triphenyl phosphine and 1-benzyl-tetrazoline-5-thione

被引：0

作者：

Pandey, R. N. ^{[1
]}

Sharma, Richa ^{[1
]}

机构：

[1] Coll Commerce, Govt Ctr Chem MU, Patna 800020, Bihar, India

来源：

ORIENTAL JOURNAL OF CHEMISTRY | 2009年 / 25卷 / 03期

关键词：

Pd-0; Pt-0; Rh+ and Ir+ complexes; Heterocyclic thioamide ligand; structure and bonding;

D O I：

暂无

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Four coordinate tetrahedral (Pd-0 and Pt-0) and square planar (Rh+ and Ir+) complexes of triphenyl phosphine and 1-benzyl tetrazoline-5-thione have been prepared and characterised on the basis of elemental analysis and spectroscopic data (IR, UV-vis, (HNMR)-H-1). Bonding of tetrazole ligand occurs through thione tautometric form. Determination of oxidation state of central metal atom in the complexes is verified by idometric and acidimetric titration.

引用

页码：609 / 613

页数：5

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