Mixed-ligand organometallic derivatives of palladium (O), platinum (O) rhodium (1) and iridium (1) with triphenyl phosphine and 1-benzyl-tetrazoline-5-thione

被引:0
|
作者
Pandey, R. N. [1 ]
Sharma, Richa [1 ]
机构
[1] Coll Commerce, Govt Ctr Chem MU, Patna 800020, Bihar, India
关键词
Pd-0; Pt-0; Rh+ and Ir+ complexes; Heterocyclic thioamide ligand; structure and bonding;
D O I
暂无
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Four coordinate tetrahedral (Pd-0 and Pt-0) and square planar (Rh+ and Ir+) complexes of triphenyl phosphine and 1-benzyl tetrazoline-5-thione have been prepared and characterised on the basis of elemental analysis and spectroscopic data (IR, UV-vis, (HNMR)-H-1). Bonding of tetrazole ligand occurs through thione tautometric form. Determination of oxidation state of central metal atom in the complexes is verified by idometric and acidimetric titration.
引用
收藏
页码:609 / 613
页数:5
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