Mixed-ligand organometallic derivatives of palladium (O), platinum (O) rhodium (1) and iridium (1) with triphenyl phosphine and 1-benzyl-tetrazoline-5-thione

被引：0

作者：

Pandey, R. N. ^{[1
]}

Sharma, Richa ^{[1
]}

机构：

[1] Coll Commerce, Govt Ctr Chem MU, Patna 800020, Bihar, India

来源：

ORIENTAL JOURNAL OF CHEMISTRY | 2009年 / 25卷 / 03期

关键词：

Pd-0; Pt-0; Rh+ and Ir+ complexes; Heterocyclic thioamide ligand; structure and bonding;

D O I：

暂无

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Four coordinate tetrahedral (Pd-0 and Pt-0) and square planar (Rh+ and Ir+) complexes of triphenyl phosphine and 1-benzyl tetrazoline-5-thione have been prepared and characterised on the basis of elemental analysis and spectroscopic data (IR, UV-vis, (HNMR)-H-1). Bonding of tetrazole ligand occurs through thione tautometric form. Determination of oxidation state of central metal atom in the complexes is verified by idometric and acidimetric titration.

引用

页码：609 / 613

页数：5

共 50 条

[31] ANALYTICAL APPLICATIONS OF MIXED-LIGAND COMPLEXES .1. INVESTIGATION OF VANADIUM(V)-PAR-H2O2 SYSTEM
SCHNEIDER, J
CSANYI, LJ
MIKROCHIMICA ACTA, 1976, 2 (3-4) : 271 - 282
[32] Transition Metal Complexes of Nitroxide Radicals. Palladium, Platinum, Pentamethylcyclopentadienyl Rhodium and Iridium Complexes, and a-Aminocarboxylate Complexes with Derivatives of 2,5-Dihydroimidazole-1-oxyls
Hintermaier, F.
Helding, S.
Volodarsky, L. B.
Suenkel, K.
Zeitschrift fuer Naturforschung. B, Journal of Chemical Sciences, 53 (01):
[33] The syntheses and structures of '3+2' and '2+2+1' oxorhenium mixed-ligand complexes employing 8-hydroxy-5-nitroquinoline as the bidentate N,O donor ligand
Chen, XY
Femia, FJ
Babich, JW
Zubieta, J
INORGANICA CHIMICA ACTA, 2000, 308 (1-2) : 80 - 90
[34] MIXED-LIGAND NICKEL(II) COMPLEXES OF 2,2'-BIPYRIDINE AND 1,10-PHENANTHROLINE WITH 3,4-DIMERCAPTOTOLUENE AS QUENCHERS OF O-1(2)
SHUKLA, S
SRIVASTAVA, TS
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1989, 48 (2-3) : 249 - 257
[35] DIAZOALKANE ACTIVATION BY IRIDIUM PHOSPHINE COMPOUNDS .1. COMPLEXES CONTAINING THE INTACT DIBENZOYLDIAZOMETHANE LIGAND AND INTERCONVERSION BETWEEN THE ETA-1-N-BOUND AND A CHELATED N,O-BOUND FORM OF THE LIGAND ACCOMPANIED BY HYDRIDE MIGRATION
COWIE, M
LOEB, SJ
MCKEER, IR
ORGANOMETALLICS, 1986, 5 (05) : 854 - 860
[36] Crystal structure and anti-cancer activity of a novel mixed-ligand complex [Pd(Phen)(Phe)]Cl • H2O1
Gao, E. J.
Liu, Q. T.
Duan, L. Y.
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2007, 33 (02) : 120 - 123
[37] Hexafluoroacetylacetonate (hfac) as ligand for pentamethylcyclopentadienyl (Cp*) rhodium and iridium complexes: Some surprising results, including an Ir3Na1O4 cubane structure
DuChane, Christine M.
Merola, Joseph S.
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2020, 929 (929)
[38] Metal complexes of biologically important ligands, CXL [1]. Halfsandwich complexes of ruthenium(II), rhodium(III), iridium(III) and palladium(II), platinum(II) complexes with N,O-chelates of fluorine and thiophene containing α-amino acids
Koch, Daniela
Beck, Wolfgang
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 2001, 56 (12): : 1271 - 1280
[39] THIO DERIVATIVES OF 1,3-DIKETONES AND THEIR METAL-COMPLEXES - NICKEL(II), PALLADIUM(II), AND PLATINUM(II) CHELATES OF O-ETHYL THIOACETOTHIOACETATE
HENDRICK.AR
MARTIN, RL
INORGANIC CHEMISTRY, 1973, 12 (11) : 2582 - 2589
[40] (η5-Cyclopentadienyl) (3-hydroxy-3-methylbut-1-ynyl-κC1)(triphenyl-phosphine-κP)nickel(II):: novel O-H•••π bonding in an organo-metallic molecule
McAdam, C. John
Robinson, Brian H.
Simpson, Jim
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2007, 63 (m338-m340): : M338 - M340

← 1 2 3 4 5 →