REACTION OF C-60 WITH DIMETHYLDIOXIRANE - FORMATION OF AN EPOXIDE AND A 1,3-DIOXOLANE DERIVATIVE

被引：187
|
作者：
ELEMES, Y [1 ]
SILVERMAN, SK [1 ]
SHEU, CM [1 ]
KAO, M [1 ]
FOOTE, CS [1 ]
ALVAREZ, MM [1 ]
WHETTEN, RL [1 ]
机构：
[1] UNIV CALIF LOS ANGELES,DEPT CHEM & BIOCHEM,LOS ANGELES,CA 90024
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 03期
关键词：
D O I：
10.1002/anie.199203511
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Not an oxygen-bridged annulene (structural type 1) but rather an epoxide (structural type 2) is the product of the reaction of dimethyldioxirane with C60. In a competing reaction, a 1,3-dioxolane (structural type 3) is formed-probably by a diradical mechanism. Cleavage of acetone from 3 leading to 2 was not observed at temperatures up to 110-degrees-C. Compound 3 could provide access to ring-opened fullerenes.
引用
收藏
页码：351 / 353
页数：3
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