REACTION OF C-60 WITH DIMETHYLDIOXIRANE - FORMATION OF AN EPOXIDE AND A 1,3-DIOXOLANE DERIVATIVE

被引：187

作者：

ELEMES, Y ^{[1
]}

SILVERMAN, SK ^{[1
]}

SHEU, CM ^{[1
]}

KAO, M ^{[1
]}

FOOTE, CS ^{[1
]}

ALVAREZ, MM ^{[1
]}

WHETTEN, RL ^{[1
]}

机构：

[1] UNIV CALIF LOS ANGELES,DEPT CHEM & BIOCHEM,LOS ANGELES,CA 90024

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 03期

关键词：

D O I：

10.1002/anie.199203511

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Not an oxygen-bridged annulene (structural type 1) but rather an epoxide (structural type 2) is the product of the reaction of dimethyldioxirane with C60. In a competing reaction, a 1,3-dioxolane (structural type 3) is formed-probably by a diradical mechanism. Cleavage of acetone from 3 leading to 2 was not observed at temperatures up to 110-degrees-C. Compound 3 could provide access to ring-opened fullerenes.

引用

页码：351 / 353

页数：3

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