REACTION OF C-60 WITH DIMETHYLDIOXIRANE - FORMATION OF AN EPOXIDE AND A 1,3-DIOXOLANE DERIVATIVE

被引：187

作者：

ELEMES, Y ^{[1
]}

SILVERMAN, SK ^{[1
]}

SHEU, CM ^{[1
]}

KAO, M ^{[1
]}

FOOTE, CS ^{[1
]}

ALVAREZ, MM ^{[1
]}

WHETTEN, RL ^{[1
]}

机构：

[1] UNIV CALIF LOS ANGELES,DEPT CHEM & BIOCHEM,LOS ANGELES,CA 90024

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 03期

关键词：

D O I：

10.1002/anie.199203511

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Not an oxygen-bridged annulene (structural type 1) but rather an epoxide (structural type 2) is the product of the reaction of dimethyldioxirane with C60. In a competing reaction, a 1,3-dioxolane (structural type 3) is formed-probably by a diradical mechanism. Cleavage of acetone from 3 leading to 2 was not observed at temperatures up to 110-degrees-C. Compound 3 could provide access to ring-opened fullerenes.

引用

页码：351 / 353

页数：3

共 50 条

[21] RADICAL-ADDITION OF 1,3-DIOXOLANE AND 2-METHYL-1,3-DIOXOLANE TO 1-HEXANE AND DIMETHYLMALEINATE
SAFIEV, OG
KRUGLOV, DE
ZLOTSKII, SS
RAKHMANKULOV, DL
IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA I KHIMICHESKAYA TEKHNOLOGIYA, 1985, 28 (07): : 33 - 36
[22] BUCKMINSTERFULLERENE (C-60) EPOXIDE
不详
APPLIED CATALYSIS A-GENERAL, 1992, 85 (01) : N2 - N3
[23] HEAT OF MIXING OF 1,3-DIOXOLANE + TRICHLOROETHYLENE
FRANCESCONI, R
COMELLI, F
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1990, 35 (03): : 291 - 293
[24] THERMOCHEMISTRY OF 1,3-DIOXOLANE OXIDATION REACTIONS
MOLERA, MJ
GARCIADOMINGUEZ, JA
ACUNA, AU
ANALES DE QUIMICA, 1975, 71 (05): : 527 - 530
[25] RADICAL TELOMERIZATION OF ETHYLENE WITH 1,3-DIOXOLANE
NAYANOV, VP
ZORIN, VV
ZLOTSKII, SS
TERENTEV, AB
RAKHMANKULOV, DL
JOURNAL OF APPLIED CHEMISTRY OF THE USSR, 1976, 48 (12): : 2863 - 2865
[26] INVESTIGATION OF EFFECTS OF A PYRIDYL AND A PIPERIDYL 1,3-DIOXOLANE DERIVATIVE ON NEUROMUSCULAR-TRANSMISSION
PINSON, RA
DRETCHEN, KL
KRUGER, GO
ARCHIVES INTERNATIONALES DE PHARMACODYNAMIE ET DE THERAPIE, 1976, 219 (01): : 52 - 63
[27] SYNTHESIS AND DECOMPOSITION OF 1,3-DIOXOLANE HYDROTRIOXIDES
KURAMSHIN, EM
KULAK, LG
ZLOTSKII, SS
RAKHMANKULOV, DL
ZHURNAL ORGANICHESKOI KHIMII, 1986, 22 (09): : 1986 - 1989
[28] CATIONIC COPOLYMERIZATION OF 1,3-DIOXOLANE WITH STYRENE
OKADA, M
YAMASHIT.Y
ISHII, Y
INTERNATIONAL CHEMICAL ENGINEERING, 1966, 6 (01): : 163 - &
[29] STUDIES ON COPOLYMERIZATION OF TRIOXANE AND 1,3-DIOXOLANE
OPITZ, G
ZEITSCHRIFT FUR CHEMIE, 1971, 11 (08): : 313 - &
[30] SYNTHESIS OF FUNCTIONALIZED POLY(1,3-DIOXOLANE)
FRANTA, E
KUBISA, P
KADA, SO
REIBEL, L
MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA, 1992, 60 : 145 - 154

← 1 2 3 4 5 →