A Mathematical Justification for the Herman-Kluk Propagator

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作者
Torben Swart
Vidian Rousse
机构
[1] Freie Universität Berlin,
[2] Institut für Mathematik,undefined
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关键词
Coherent State; Canonical Transformation; Semiclassical Limit; Fourier Integral Operator; Zeroth Order Term;
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摘要
A class of Fourier Integral Operators which converge to the unitary group of the Schrödinger equation in the semiclassical limit ε → 0 in the uniform operator norm is constructed. The convergence allows for an error bound of order O(ε), which can be improved to arbitrary order in ε upon the introduction of corrections in the symbol. On the Ehrenfest-timescale, the result holds with a slightly weaker error bound. In the chemical literature the approximation is known as the Herman-Kluk propagator.
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