1-benzyl-4-aza-1-azoniabicyclo[2.2.2] octane tribromide as a highly reactive brominating agent for aniline derivatives

被引：10
|
作者：
Hajipour, AR [1 ]
Imanieh, H
Pourmousavi, SA
机构：
[1] Isfahan Univ Technol, Pharmaceut Res Lab, Coll Chem, Esfahan 84156, IR, Iran
[2] Imam Khomeini Int Univ, Dept Chem, Fac Sci, Gazvin, IR, Iran
来源：
SYNTHETIC COMMUNICATIONS | 2004年 / 34卷 / 24期
关键词：
aniline; bromination; tribromide;
D O I：
10.1081/SCC-200043274
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Reaction of anilines with 1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane tribromide (3) in the presence of CaCO3 in small amounts of methanol gave brominated aromatic amines in good yields at room temperature. The isolation of products is straightforward.
引用
收藏
页码：4597 / 4604
页数：8
相关论文
共 50 条
  • [41] Complex of 1-hexadecyl-4-aza-1-azoniabicyclo[2.2.2]octane bromide with copper dibromide: structure, aggregation, and biological activity
    E. P. Zhil´tsova
    M. R. Ibatullina
    S. S. Lukashenko
    T. N. Pashirova
    A. D. Voloshina
    V. V. Zobov
    S. A. Ziganshina
    M. P. Kutyreva
    L. Ya. Zakharova
    Russian Chemical Bulletin, 2016, 65 : 1365 - 1371
  • [42] Metallomicellar Systems Based on the Complexes of 1-Hexadecyl-4-aza-1-azoniabicyclo[2.2.2]octane Bromide with Transition Metal Nitrates
    M. R. Ibatullina
    E. P. Zhil’tsova
    S. S. Lukashenko
    A. D. Voloshina
    A. S. Sapunova
    O. A. Lenina
    I. R. Nizameev
    M. P. Kutyreva
    L. Ya. Zakharova
    Russian Journal of General Chemistry, 2018, 88 : 2359 - 2367
  • [43] Metallomicellar Systems Based on the Complexes of 1-Hexadecyl-4-aza-1-azoniabicyclo[2.2.2]octane Bromide with Transition Metal Nitrates
    Ibatullina, M. R.
    Zhil'tsova, E. P.
    Lukashenko, S. S.
    Voloshina, A. D.
    Sapunova, A. S.
    Lenina, O. A.
    Nizameev, I. R.
    Kutyreva, M. P.
    Zakharova, L. Ya.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2018, 88 (11) : 2359 - 2367
  • [44] Complex of 1-hexadecyl-4-aza-1-azoniabicyclo[2.2.2]octane bromide with copper dibromide: structure, aggregation, and biological activity
    Zhil'tsova, E. P.
    Ibatullina, M. R.
    Lukashenko, S. S.
    Pashirova, T. N.
    Voloshina, A. D.
    Zobov, V. V.
    Ziganshina, S. A.
    Kutyreva, M. P.
    Zakharova, L. Ya.
    RUSSIAN CHEMICAL BULLETIN, 2016, 65 (05) : 1365 - 1371
  • [45] Deprotection of thioacetal using 1-butyl-4-aza-1-azoniabicyclo[2.2.2] octane dichromate (BABOD) in the presence of AlCl3
    Hajipour, Abdol R.
    Bagheri, Hamid
    Ruoho, Arnold E.
    JOURNAL OF CHEMICAL RESEARCH, 2005, (06) : 372 - 374
  • [46] 1-butyl-4-aza-1-azoniabicyclo[2.2.2]octane dichromate (BAAOD): An efficient and novel reagent for oxidation of sulfides to the corresponding sulfoxides
    Hajipour, AR
    Bagheri, HR
    Ruoho, AE
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2003, 178 (11) : 2441 - 2446
  • [47] Oxidation of alcohols with 1-decyl-4-aza-1-azoniabicyclo[2.2.2]-octane chlorochromate under conventional and solvent-free conditions
    Hajipour, A. R.
    Bagheri, H. R.
    Ruoho, A. E.
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2006, 42 (06) : 844 - 848
  • [48] Oxidation of alcohols with 1-butyl-4-aza-1-azoniabicyclo[2.2.2] octane chlorochromate (BAAOCC) under non-aqueous conditions
    Hajipour, AR
    Bagheri, HR
    Ruoho, AE
    INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 2005, 44 (03): : 577 - 580
  • [49] Spectrophotometric study of quercetin in metallomicellar solutions of 1-hexadecyl-4-aza-1-azoniabicyclo[2.2.2]octane bromide complex with copper dibromide
    Zhiltsova, Elena P.
    Ibatullina, Marina R.
    Lukashenko, Svetlana S.
    Kutyreva, Marianna P.
    Zakharova, Lucia Ya.
    JOURNAL OF MOLECULAR LIQUIDS, 2018, 249 : 716 - 722
  • [50] Supramolecular system 4-aza-1-hexadecyl-1-azoniabicyclo[2.2.2]octane bromide—sodium salicylate. Aggregation and rheological properties
    F. G. Valeeva
    D. A. Kuryashov
    S. V. Zakharov
    G. I. Vagapova
    E. A. Vasilieva
    N. Yu. Bashkirtseva
    L. Ya. Zakharova
    A. I. Konovalov
    Russian Chemical Bulletin, 2013, 62 : 989 - 993
12345