1-benzyl-4-aza-1-azoniabicyclo[2.2.2] octane tribromide as a highly reactive brominating agent for aniline derivatives

被引:10
|
作者
Hajipour, AR [1 ]
Imanieh, H
Pourmousavi, SA
机构
[1] Isfahan Univ Technol, Pharmaceut Res Lab, Coll Chem, Esfahan 84156, IR, Iran
[2] Imam Khomeini Int Univ, Dept Chem, Fac Sci, Gazvin, IR, Iran
关键词
aniline; bromination; tribromide;
D O I
10.1081/SCC-200043274
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Reaction of anilines with 1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane tribromide (3) in the presence of CaCO3 in small amounts of methanol gave brominated aromatic amines in good yields at room temperature. The isolation of products is straightforward.
引用
收藏
页码:4597 / 4604
页数:8
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