Bis[tris(1-pyrazolyl)methane-κ3N,N′,N"]copper(II) dichloride methanol disolvate

被引：9
|
作者：
Silva, Telma F. S. [1 ]
Martins, Luisa M. D. R.
da Silva, M. Fatima C. Guedes
Pombeiro, Armando J. L.
机构：
[1] Inst Super Engn Lisboa, Area Cient Fis, P-1950062 Lisbon, Portugal
[2] Inst Super Engn Lisboa, Dept Engn Quim, P-1950062 Lisbon, Portugal
[3] Univ Tecn Lisboa, Ctr Quim Estrutural, Inst Super Tecn, P-1049001 Lisbon, Portugal
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2007年 / 63卷
关键词：
D O I：
10.1107/S1600536807024671
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The reaction between copper(II) chloride dihydrate and excess tris(1-pyrazolyl) methane results in the formation of the title complex, [Cu(C10H10N6)(2)]Cl-2 center dot 2CH(3)OH. The centrosymmetric complex cation is mononuclear with octahedral coordination for Cu and two tridentate ligands. Two short and one long Cu-N distances [2.002 (3), 2.011 (2) and 2.413 (2) angstrom] are found, as expected for Jahn-Teller distortion.
引用
收藏
页码：M1979 / U1707
页数：9
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