Bis[μ-bis(diphenylphosphino)methane-κ2P:P′]bis[(2,2′-bipyridine-κ2N,N′)copper(I)]bis(tetrafluoridoborate)diethyl ether disolvate

被引：0
|
作者：
Mo, Juan [1 ]
Zhang, Su-Mei
Ge, Wen-Zhong
Liu, Jian-Hua
机构：
[1] Henan Agr Univ, Coll Anim Husb & Vet Sci, Zhengzhou 450002, Henan, Peoples R China
[2] Heilongjiang August First Land Reclamat Univ, Coll Life Sci & Biotechnol, Daqing 163319, Heilongjiang, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷
关键词：
D O I：
10.1107/S1600536807032539
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The dinuclear cation of the title complex, [Cu-2(C25H22P2)(2)(-)(C10H8N2)(2)](BF4)(2)center dot 2C(4)H(10)O, lies on a centre of inversion. Each Cut atom is coordinated by 2,2'-bipyridine (bpy) and bis(diphenylphosphino)methane (dppm) ligands, and has a distorted tetrahedral coordination geometry. The distance between the two Cu-I atoms separated by two dppm bridging ligands is 4.671 (3) angstrom. The solvent molecule and anion are each disordered over two positions; the site occupancy factor ratios are ca 0.56:0.44 and 0.6:0.4, respectively.
引用
收藏
页码：M2096 / U658
页数：14
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