Bis[tris(1-pyrazolyl)methane-κ3N,N′,N"]copper(II) dichloride methanol disolvate

被引：9

作者：

Silva, Telma F. S. ^{[1
]}

Martins, Luisa M. D. R.

da Silva, M. Fatima C. Guedes

Pombeiro, Armando J. L.

机构：

[1] Inst Super Engn Lisboa, Area Cient Fis, P-1950062 Lisbon, Portugal

[2] Inst Super Engn Lisboa, Dept Engn Quim, P-1950062 Lisbon, Portugal

[3] Univ Tecn Lisboa, Ctr Quim Estrutural, Inst Super Tecn, P-1049001 Lisbon, Portugal

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2007年 / 63卷

关键词：

D O I：

10.1107/S1600536807024671

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The reaction between copper(II) chloride dihydrate and excess tris(1-pyrazolyl) methane results in the formation of the title complex, [Cu(C10H10N6)(2)]Cl-2 center dot 2CH(3)OH. The centrosymmetric complex cation is mononuclear with octahedral coordination for Cu and two tridentate ligands. Two short and one long Cu-N distances [2.002 (3), 2.011 (2) and 2.413 (2) angstrom] are found, as expected for Jahn-Teller distortion.

引用

页码：M1979 / U1707

页数：9

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