Syntheses and X-ray structures of (2,2′-biphosphinine)-(η5-pentamethylcyclopentadienyl)ruthenium(I) dimer and ruthenium(0) complexes

被引：18
|
作者：
Rosa, P [1 ]
Ricard, L [1 ]
Mathey, F [1 ]
Le Floch, P [1 ]
机构：
[1] Ecole Polytech, Lab Heteroelements & Coodinat, CNRS, UMR 7653, F-91128 Palaiseau, France
来源：
ORGANOMETALLICS | 2000年 / 19卷 / 24期
关键词：
D O I：
10.1021/om0004491
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reduction of the [Ru(Cp*)(tmbp) Cl] complex (tmbp = 4,4',5,5'-tetramethyl-2,2'-biphosphinine) with 1 and 2 equiv of sodium naphthalenide respectively yield a dimeric (Ru(Cp*)(tmbp)](2) complex and a (Ru(Cp*) (tmbp)][Na(DME)(2)] complex: which were both structurally characterized. Trapping the Ru(0) complex with MeI, Ph3SnCl, Me3SnCl, or H+ affords the corresponding Ru(II) derivatives.
引用
收藏
页码：5247 / 5250
页数：4
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