Syntheses and X-ray structures of (2,2′-biphosphinine)-(η5-pentamethylcyclopentadienyl)ruthenium(I) dimer and ruthenium(0) complexes

被引：18
|
作者：
Rosa, P [1 ]
Ricard, L [1 ]
Mathey, F [1 ]
Le Floch, P [1 ]
机构：
[1] Ecole Polytech, Lab Heteroelements & Coodinat, CNRS, UMR 7653, F-91128 Palaiseau, France
来源：
ORGANOMETALLICS | 2000年 / 19卷 / 24期
关键词：
D O I：
10.1021/om0004491
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reduction of the [Ru(Cp*)(tmbp) Cl] complex (tmbp = 4,4',5,5'-tetramethyl-2,2'-biphosphinine) with 1 and 2 equiv of sodium naphthalenide respectively yield a dimeric (Ru(Cp*)(tmbp)](2) complex and a (Ru(Cp*) (tmbp)][Na(DME)(2)] complex: which were both structurally characterized. Trapping the Ru(0) complex with MeI, Ph3SnCl, Me3SnCl, or H+ affords the corresponding Ru(II) derivatives.
引用
收藏
页码：5247 / 5250
页数：4
相关论文
共 50 条
  • [21] Reactions of iridium and ruthenium arenethiolato complexes with propylene sulfide.: X-ray structures of 1-arylthio-2-propanethiolato-S,S′ iridium and ruthenium complexes
    Matsukawa, S
    Kuwata, S
    Hidai, M
    INORGANIC CHEMISTRY COMMUNICATIONS, 1998, 1 (10) : 368 - 371
  • [22] SYNTHESIS AND SPECTROSCOPIC STUDIES OF MOLYBDENUM (0) AND RUTHENIUM(II) COMPLEXES OF 2,2'-DIPYRIDYLAMINE(+)
    ISHAQ, M
    BAGHLAF, AO
    ALKHATERY, MI
    ALANQUARY, Y
    JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN, 1993, 15 (01): : 36 - 38
  • [23] Synthesis, structure, reactivity, and electrochemical study of a (2,2'-biophosphinine) (η5-pentamethylcyclopentadienyl)chlororuthenium(II)comple x
    Floch, Pascal Le
    Mansuy, Stephane
    Richard, Louis
    Mathey, Francois
    Jutand, Anny
    Amatore, Christian
    Organometallics, 1996, 15 (15):
  • [24] Syntheses and X-ray structural analyses of the mononuclear tungsten hexacarbonyl complexes of 2,2′-bipyridine and 2,2′-bipyrimidine
    Chapman, J
    Kolawole, G
    Long, N
    White, AJP
    Williams, DJ
    O'Brien, P
    SOUTH AFRICAN JOURNAL OF SCIENCE, 2005, 101 (9-10) : 454 - 456
  • [25] Electronic structures of organometallic complexes of f elements LXXVI: Correlation of experimental and calculated (on the basis of density functional theory) vibrational spectra of bis(η5-cyclopentadienyl)ruthenium and bis(η5-pentamethylcyclopentadienyl)ruthenium
    Prosenc, Marc Heinrich
    Reddmann, Hauke
    Amberger, Hanns-Dieter
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2012, 87 : 126 - 134
  • [26] (Acetonitrile-N)(η4-2-methylbuta-1,3-diene)(η5-pentamethylcyclopentadienyl)-ruthenium(II) trifluoromethanesulfonate
    Gemel, C
    Kirchner, K
    Schmid, R
    Mereiter, K
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1999, 55 : 2053 - 2055
  • [27] TRIMETHYLPHOSPHINE COMPLEXES OF RHODIUM(I) AND RUTHENIUM(II) - X-RAY CRYSTAL-STRUCTURES OF "CHLOROTRISTRIMETHYLPHOSPHINERHODIUM AND TETRAKISTRIMETHYLPHOSPHINERHODIUM CHLORIDE
    JONES, RA
    REAL, FM
    WILKINSON, G
    GALAS, AMR
    HURSTHOUSE, MB
    MALIK, KMA
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1979, (11) : 489 - 490
  • [28] Syntheses, structures, and reactions of rhenium and ruthenium carbonyl derivatives of 2,2′-bis(indenyl)propane
    Zhu, Bo-Lin
    Shi, Wei
    Chen, Yun-Fei
    Li, Yuan
    Hao, Xiao-Ting
    INORGANICA CHIMICA ACTA, 2013, 405 : 485 - 492
  • [29] Synthesis and X-ray Structures of Potential Light-Harvesting Ruthenium(II) Complexes
    Mariappan, Kadarkaraisamy
    Hussain, Anwar
    Nisly, Nathaniel
    Henning, Tanner J. J.
    Goerl, Kathryn A. A.
    Alaparthi, Madhubabu
    Sykes, Andrew G. G.
    MOLBANK, 2023, 2023 (02)
  • [30] Preparation, characterization and X-ray crystallographic analysis of η5- and η6-mono-ruthenium(II) complexes of 2,3-bis(2,2′-bipyridyl)quinoxaline
    Heirtzler, F
    Jones, P
    Neuburger, M
    Zehnder, M
    POLYHEDRON, 1999, 18 (3-4) : 601 - 608
12345