Syntheses and X-ray structures of (2,2′-biphosphinine)-(η5-pentamethylcyclopentadienyl)ruthenium(I) dimer and ruthenium(0) complexes

被引：18

作者：

Rosa, P ^{[1
]}

Ricard, L ^{[1
]}

Mathey, F ^{[1
]}

Le Floch, P ^{[1
]}

机构：

[1] Ecole Polytech, Lab Heteroelements & Coodinat, CNRS, UMR 7653, F-91128 Palaiseau, France

来源：

ORGANOMETALLICS | 2000年 / 19卷 / 24期

关键词：

D O I：

10.1021/om0004491

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reduction of the [Ru(Cp*)(tmbp) Cl] complex (tmbp = 4,4',5,5'-tetramethyl-2,2'-biphosphinine) with 1 and 2 equiv of sodium naphthalenide respectively yield a dimeric (Ru(Cp*)(tmbp)](2) complex and a (Ru(Cp*) (tmbp)][Na(DME)(2)] complex: which were both structurally characterized. Trapping the Ru(0) complex with MeI, Ph3SnCl, Me3SnCl, or H+ affords the corresponding Ru(II) derivatives.

引用

页码：5247 / 5250

页数：4

共 50 条

[31] RUTHENIUM CARBONYL-COMPLEXES .3. PREPARATIONS, PROPERTIES AND STRUCTURES OF DICARBONYL AND MONOCARBONYL-(2,2'-6',2'-TERPYRIDYL)RUTHENIUM(II) COMPLEXES
DEACON, GB
PATRICK, JM
SKELTON, BW
THOMAS, NC
WHITE, AH
AUSTRALIAN JOURNAL OF CHEMISTRY, 1984, 37 (05) : 929 - 945
[32] Ruthenium(II) complexes of novel 4′-ethoxy- and 4′-hydroxy-5,5"-dimethyl-2,2′:6′,2"-terpyridines:: X-ray crystal structures of 4′-ethoxy-5,5"-dimethyl-2,2":6′,2"-terpyridine and the ruthenium(II) complex of 4′-ethoxy-5,5"-dimethyl-2,2′:6′,2"-terpyridine with 4′-chloro-2,2′:6′,2"'-terpyridine
Fallahpour, RA
Neuburger, M
Zehnder, M
POLYHEDRON, 1999, 18 (18) : 2445 - 2454
[33] Synthesis and X-ray structures of hydridotris(1-pyrazolyl) borate carbonyl complexes of ruthenium
Shiu, KB
Chen, JY
Yu, SJ
Wang, SL
Liao, FL
Wang, Y
Lee, GH
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2002, 648 (1-2) : 193 - 203
[34] Synthesis and x-ray structures of some mono- and binuclear ruthenium complexes with bisphosphine ligands
Mauthner, K
Kalt, D
Slugovc, C
Mereiter, K
Schmid, R
Kirchner, K
MONATSHEFTE FUR CHEMIE, 1997, 128 (6-7): : 533 - 540
[35] SYNTHESIS AND CHARACTERIZATION OF POLYPYRIDINE RUTHENIUM(II) COMPLEXES CONTAINING S-BONDED THIOETHER LIGANDS - X-RAY CRYSTAL-STRUCTURES OF CIS-BIS(2,2'-BIPYRIDINE)BIS(PHENOTHIAZINE-S)RUTHENIUM(II) AND TRANS-BIS(2,2'-BIPYRIDINE)BIS(PHENOTHIAZINE-S)RUTHENIUM(II) HEXAFLUOROPHOSPHATES
KROENER, R
HEEG, MJ
DEUTSCH, E
INORGANIC CHEMISTRY, 1988, 27 (03) : 558 - 566
[36] Three ruthenocene derivatives:: (η5-4,7-dimethylindenyl)(η5-penta-methylcyclopentadienyl)ruthenium(II), [n5-[2](4,7)indeno[2]paracyclophanyl]-(η5-pentamethylcyclopentadienyl)-ruthenium(II) and bis[η5-[2](4,7)-indeno[2]paracyclophanyl]-ruthenium(II)
Jones, PG
Hartig, T
Hopf, H
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2002, 58 (06) : M347 - M350
[37] CHLORO(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM AND HYDRIDO(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM COMPLEXES - ANOMALOUS NMR BEHAVIOR OF C5ME5RUH3PR3 (R = CHME2, CY)
ARLIGUIE, T
BORDER, C
CHAUDRET, B
DEVILLERS, J
POILBLANC, R
ORGANOMETALLICS, 1989, 8 (05) : 1308 - 1314
[38] Zn(II), Cd(II) and Hg(II) complexes with 2,2′-biquinoline, syntheses and X-ray crystal structures of [Hg(bq)(SCN)2]
Morsali, A
Mahjoub, AR
Ramazani, A
JOURNAL OF COORDINATION CHEMISTRY, 2004, 57 (04) : 347 - 352
[39] The first triisopropylstibane ruthenium(II) and ruthenium(O) complexes including the X-ray crystal structure of [Ru(eta(3)-C3H5)(2)(SbiPr(3))(2)]
Werner, H
Grunwald, C
Laubender, M
Gevert, O
CHEMISCHE BERICHTE, 1996, 129 (10) : 1191 - 1194
[40] MONONUCLEAR(MU(6)-ARENE)RUTHENIUM(II) AND (ETA(5)-PENTAMETHYLCYCLOPENTADIENYL)RHODIUM(III) AND BINUCLEAR RUTHENIUM(II) PLATINUM(II) AND RUTHENIUM(II) RHODIUM(I) COMPLEXES CONTAINING 2-(DIPHENYLPHOSPHINO)PYRIDINE
DROMMI, D
ARENA, CG
NICOLO, F
BRUNO, G
FARAONE, F
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 485 (1-2) : 115 - 121

← 1 2 3 4 5 →