Reaction of rhodium trichloride with P-functionalized calix[4]resorcinols in various media

被引：4
|
作者：
Guseva, E. V. [1 ]
Morozov, V. I. [2 ]
Karimova, D. T. [1 ]
Gavrilova, E. L. [1 ]
Naumova, A. A. [1 ]
Polovnyak, V. K. [1 ]
Krasil'nikova, E. A. [1 ]
机构：
[1] Kazan State Technol Univ, Kazan 420015, Tatarstan, Russia
[2] Russian Acad Sci, Kazan Res Ctr, AE Arbuzov Organ & Phys Chem Inst, Kazan 420088, Tatarstan, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2010年 / 80卷 / 01期
基金：
俄罗斯基础研究基金会;
关键词：
COMPLEXES; SPECTRA; DIOXYGEN;
D O I：
10.1134/S1070363210010081
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The features of the reaction of rhodium trichloride with calix[4]resorcinols modified with various types of phosphorus-containing groups in ethanol, ethanol-formate medium and acetone under an inert atmosphere were studied. Neutral complexes were isolated in the solid form, the solvent molecules were shown to be actively involved into the formation of the final reaction products. The compounds were characterized by IR, Raman, P-31 NMR, ESR, X-ray photoelectron and electronic spectroscopy, and electric conductivity. The composition was confirmed by the data of elemental analysis, X-ray fluorescence analysis, and derivatography. Based on the analysis of the ESR spectrum, the electronic and geometric structures of the paramagnetic product isolated from the acetone medium was determined.
引用
收藏
页码：47 / 59
页数：13
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