Reaction of rhodium trichloride with P-functionalized calix[4]resorcinols in various media

被引：4

作者：

Guseva, E. V. ^{[1
]}

Morozov, V. I. ^{[2
]}

Karimova, D. T. ^{[1
]}

Gavrilova, E. L. ^{[1
]}

Naumova, A. A. ^{[1
]}

Polovnyak, V. K. ^{[1
]}

Krasil'nikova, E. A. ^{[1
]}

机构：

[1] Kazan State Technol Univ, Kazan 420015, Tatarstan, Russia

[2] Russian Acad Sci, Kazan Res Ctr, AE Arbuzov Organ & Phys Chem Inst, Kazan 420088, Tatarstan, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2010年 / 80卷 / 01期

基金：

俄罗斯基础研究基金会;

关键词：

COMPLEXES; SPECTRA; DIOXYGEN;

D O I：

10.1134/S1070363210010081

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The features of the reaction of rhodium trichloride with calix[4]resorcinols modified with various types of phosphorus-containing groups in ethanol, ethanol-formate medium and acetone under an inert atmosphere were studied. Neutral complexes were isolated in the solid form, the solvent molecules were shown to be actively involved into the formation of the final reaction products. The compounds were characterized by IR, Raman, P-31 NMR, ESR, X-ray photoelectron and electronic spectroscopy, and electric conductivity. The composition was confirmed by the data of elemental analysis, X-ray fluorescence analysis, and derivatography. Based on the analysis of the ESR spectrum, the electronic and geometric structures of the paramagnetic product isolated from the acetone medium was determined.

引用

页码：47 / 59

页数：13

共 50 条

[31] Sensing abilities of functionalized calix[4]arene coated QCM sensors towards volatile organic compounds in aqueous media
Temel, Farabi
Ozcelik, Egemen
Ture, Ayse Gul
Tabakci, Mustafa
APPLIED SURFACE SCIENCE, 2017, 412 : 238 - 251
[32] Reaction of rhodium trichloride and dirhodium(II) acetate with trans-4,4′-bis(diethoxyphosphoryl)biphenyl-18-crown-6
E. V. Guseva
A. A. Naumova
D. T. Karimova
A. V. Sokolova
E. L. Gavrilova
T. E. Busygina
Russian Journal of General Chemistry, 2012, 82 : 1 - 8
[33] Reaction of rhodium trichloride and dirhodium(II) acetate with trans-4,4'-bis(diethoxyphosphoryl)biphenyl-18-crown-6
Guseva, E. V.
Naumova, A. A.
Karimova, D. T.
Sokolova, A. V.
Gavrilova, E. L.
Busygina, T. E.
RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2012, 82 (01) : 1 - 8
[34] α-Methylbenzylamine Functionalized Crown-Ether-Appended Calix[4]arene Phase Transfer Catalyst for Enantioselective Henry Reaction
Malik, Apoorva
Sharma, Pragati R.
Sharma, Rakesh K.
CHEMISTRY-A EUROPEAN JOURNAL, 2023, 29 (72)
[35] Comparative Study of Tributyltin Adsorption onto Mesoporous Silica Functionalized with Calix[4]arene, p-tert-Butylcalix[4]arene and p-Sulfonatocalix[4]arene
Alahmadi, Sana
Mohamad, Sharifah
Maah, Mohd Jamil
MOLECULES, 2014, 19 (04): : 4524 - 4547
[36] p-Sulfonic acid calix[4]arene-functionalized alkyl-bridged organosilica in esterification reactions
de Assis, J. V.
Abranches, P. A. S.
Braga, I. B.
Zuniga, O. M. P.
Sathicq, A. G.
Romanelli, G. P.
Sato, A. G.
Fernandes, S. A.
RSC ADVANCES, 2016, 6 (29): : 24285 - 24289
[37] Atomically Dispersed ZnN4 Sites Anchored on P-Functionalized Carbon with Hierarchically Ordered Porous Structures for Boosted Electroreduction of CO2
Hu, Chenghong
Yao, Wen
Yang, Xianfeng
Shen, Kui
Chen, Liyu
Li, Yingwei
ADVANCED SCIENCE, 2024, 11 (04)
[38] Stereoisomerism and complexation behaviour of functionalized p-tert-calix[6]-1,4-2,5-biscrown-4
Guan, B
Gong, SL
Wu, XJ
Chen, YY
TETRAHEDRON LETTERS, 2005, 46 (36) : 6041 - 6044
[39] Synthesis and Properties of Mixed Functionalized p-tert-Butyl Calix[4,6]Arene Derivatives with Ionophore Properties
Saponar, Alina
Popovici, Elisabeth-Jeanne
Nemes, Gabriela
Popovici, Nicolae
Perhaita, Ioana
Bica, Ecaterina
Silaghi-Dumitrescu, Ioan
REVISTA DE CHIMIE, 2012, 63 (03): : 249 - 254
[40] Ultrasensitive and specific detection of dimethoate using a p-sulphonato-calix[4]resorcinarene functionalized silver nanoprobe in aqueous solution
Menon, Shobhana K.
Modi, Nishith R.
Pandya, Alok
Lodha, Anand
RSC ADVANCES, 2013, 3 (27) : 10623 - 10627

← 1 2 3 4 5 →