Reaction of rhodium trichloride and dirhodium(II) acetate with trans-4,4′-bis(diethoxyphosphoryl)biphenyl-18-crown-6

被引：0
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作者：
E. V. Guseva
A. A. Naumova
D. T. Karimova
A. V. Sokolova
E. L. Gavrilova
T. E. Busygina
机构：
[1] Kazan State Technological University,
来源：
Russian Journal of General Chemistry | 2012年 / 82卷
关键词：
Rhodium; Crown Ether; Phosphoryl Group; Diethoxyphosphoryl; Rhodium Atom;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The complexation of RhCl3·3H2O and [RH2(CH3COO)4·2H2O] with trans-4,4′-bis (diethoxyphosphoryl)biphenyl-18-crown-6 in various media was studied. In the synthesized compounds the rhodium(III) or dirodium(II) ions form supramolecular ensembles with ligand environment. The compounds were characterized by NMR, IR, Raman, ESR, X-ray electron spectroscopy, conductivity, and the data of elemental and X-ray fluorescence analyses. The predominant role of diethoxyphosphoryl groups at the macrocycle in binding rhodium(III) and dirhodium(II) ions was demonstrated.
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页码：1 / 8
页数：7
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