Polymeric disodium (μ-trans-4,4′-ethylenedipyridyl)bis[μ-5-sulfoisophthalato(3-)]-dicadmate(II) hexahydrate

被引:8
|
作者
Tao, J
Yin, X
Huang, RB
Zheng, LS
Ng, SW [1 ]
机构
[1] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia
[2] Xiamen Univ, Dept Chem, Xiamen 361005, Peoples R China
关键词
D O I
10.1107/S1600536803015289
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title crystal structure, {Na-2[Cd-2(C12H10N2)(C8H3O7S)(2)].-6H(2)O}(n), contains pentagonal-bipyramidal Cd atoms and octahedral Na atoms. The Cd atom is chelated by two carboxyl groups of adjacent 5-sulfoisophthalate(3-) trianions, and it is also coordinated by the pyridyl group of the centrosymmetric heterocycle, the coordinating atoms comprising the pentagonal plane around the metal atom. In the network structure, the Na atoms occupy the voids in the network such that they exist in a six-coordinate geometry.
引用
收藏
页码:M611 / M613
页数:3
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