Reaction of rhodium trichloride and dirhodium(II) acetate with trans-4,4′-bis(diethoxyphosphoryl)biphenyl-18-crown-6

被引：0

作者：

E. V. Guseva

A. A. Naumova

D. T. Karimova

A. V. Sokolova

E. L. Gavrilova

T. E. Busygina

机构：

[1] Kazan State Technological University,

来源：

Russian Journal of General Chemistry | 2012年 / 82卷

关键词：

Rhodium; Crown Ether; Phosphoryl Group; Diethoxyphosphoryl; Rhodium Atom;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The complexation of RhCl3·3H2O and [RH2(CH3COO)4·2H2O] with trans-4,4′-bis (diethoxyphosphoryl)biphenyl-18-crown-6 in various media was studied. In the synthesized compounds the rhodium(III) or dirodium(II) ions form supramolecular ensembles with ligand environment. The compounds were characterized by NMR, IR, Raman, ESR, X-ray electron spectroscopy, conductivity, and the data of elemental and X-ray fluorescence analyses. The predominant role of diethoxyphosphoryl groups at the macrocycle in binding rhodium(III) and dirhodium(II) ions was demonstrated.

引用

页码：1 / 8

页数：7

共 48 条

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