Ligand bite angle effects in metal-catalyzed C-C bond formation

被引：924

作者：

van Leeuwen, PWNM ^{[1
]}

Kamer, PCJ ^{[1
]}

Reek, JNH ^{[1
]}

Dierkes, P ^{[1
]}

机构：

[1] Univ Amsterdam, Inst Mol Chem, NL-1018 WV Amsterdam, Netherlands

来源：

CHEMICAL REVIEWS | 2000年 / 100卷 / 08期

关键词：

D O I：

10.1021/cr9902704

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This review demonstrates that the bite angle of bidentate ligands is an important parameter that has a pronounced effect on rate and selectivity of metal-catalyzed reactions. It is shown that the bite angle gives unprecedented selectivities and reactivities in several important reactions.

引用

页码：2741 / 2769

页数：29

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