Transition Metal-Catalyzed Electroreductive Cross-Couplings for C-C Bond Formation

被引:6
|
作者
Gao, Meng-Yu [1 ]
Gosmini, Corinne [1 ]
机构
[1] Ecole Polytech, Inst Polytech Paris, Lab Chim Mol LCM, CNRS, F-91120 Palaiseau, France
关键词
electroreduction; cobalt; nickel; cross-coupling; C-C bond; FUNCTIONALIZED ARYL HALIDES; ALKYL-HALIDES; ELECTROCHEMICAL VINYLATION; REDUCTIVE ALLYLATION; HETEROARYL HALIDES; ALLYLIC ACETATES; COBALT CATALYSIS; NICKEL-COMPLEXES; AROMATIC HALIDES; ARYLATION;
D O I
10.1002/ijch.202300074
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This mini review provides an overview of a range of Ni-, Co- and Pd-catalyzed electroreductive cross-coupling reactions. The combination of homogeneous transition-metal catalysis and electrochemistry are green alternatives to traditional reductive cross-coupling reactions to form Csp(2)-Csp(2), Csp(2)-Csp(3) and some Csp(3)-Csp(3) bonds in one step. Most of these reactions use the sacrificial anode process.
引用
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页数:9
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