Transition metal-catalyzed C-C bond formation reactions using alkyl halides

被引：88
|
作者：
Terao, Jun
Kambe, Nobuaki
机构：
[1] Osaka Univ, Dept Appl Chem, Grad Sch Engn, Suita, Osaka 5650871, Japan
[2] Osaka Univ, Ctr Atom & Mol Technol, Grad Sch Engn, Suita, Osaka 5650871, Japan
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2006年 / 79卷 / 05期
关键词：
D O I：
10.1246/bcsj.79.663
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This account reviews transition metal-catalyzed C-C bond formation reactions using alkyl halides, which have rarely been used as carbon sources in conventional transition metal-catalyzed systems. In the reactions, ate complexes formed by the reaction of transition metals with a Grignard reagent play important roles as the active catalytic species. The reactions mentioned here are mechanistically new and provide a promising methodology for the construction of carbon frameworks employing alkyl halides.
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收藏
页码：663 / 672
页数：10
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