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Metal-catalyzed release of supported boronic acids for C-C bond formation
被引:49
|作者:
Pourbaix, C
[1
]
Carreaux, F
[1
]
Carboni, B
[1
]
机构:
[1] Univ Rennes 1, CNRS, UMR 6510, F-35042 Rennes, France
关键词:
D O I:
10.1021/ol000338y
中图分类号:
O62 [有机化学];
学科分类号:
070303 ;
081704 ;
摘要:
[GRAPHICS] The viability of solid-supported boronic acids as reagents for Suzuki couplings and nucleophilic additions to aldehydes and enones was successfully demonstrated. This metal-catalyzed cleavage strategy allows the synthesis of a series of functionalized biphenyl products, benzylic alcohols, and beta -substituted ketones.
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页码:803 / 805
页数:3
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