Intermolecular rhodium(II)-catalyzed reactions with silicon-substituted carbonyl ylides

被引:15
|
作者
Bolm, C [1 ]
Saladin, S [1 ]
Kasyan, A [1 ]
机构
[1] Rhein Westfal TH Aachen, Inst Organ Chem, D-52056 Aachen, Germany
关键词
D O I
10.1021/ol026987m
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The Rh(II)-catalyzed reaction of benzyl 2-trialkylsilyi-2-diazoacetates with various acyclic and cyclic ketones affords novel dioxolanones via silicon-substituted carbonyl ylides in up to 98% yield.
引用
收藏
页码:4631 / 4633
页数:3
相关论文
共 50 条
  • [41] REACTIONS OF ALPHA-SUBSTITUTED CARBONYL-STABILIZED SULFONIUM YLIDES WITH SUCCINIC ANHYDRIDE
    MUKAIYAM.T
    HAGIO, K
    TAKEI, H
    SAIGO, K
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1971, 44 (01) : 161 - +
  • [42] Metal-catalyzed cyclization reactions of carbonyl ylides:: Synthesis and DFT study of mechanisms
    Celik, Mehmet A.
    Yurtsever, Mine
    Tuezuen, Nurcan S.
    Guengoer, Fuesun S.
    Sezer, Oezkan
    Anac, Olcay
    ORGANOMETALLICS, 2007, 26 (12) : 2978 - 2985
  • [43] Reactions of silicon hydrides catalyzed by rhodium(III) sulfoxide complexes
    Eliseeva, A. A.
    Prudnikova, E. G.
    Panikorovskii, T. L.
    Skvortsov, N. K.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2017, 87 (08) : 1884 - 1886
  • [44] Reactions of silicon hydrides catalyzed by rhodium(III) sulfoxide complexes
    A. A. Eliseeva
    E. G. Prudnikova
    T. L. Panikorovskii
    N. K. Skvortsov
    Russian Journal of General Chemistry, 2017, 87 : 1884 - 1886
  • [45] Rhodium(II)-Catalyzed Denitrogenative Annulation for the Synthesis of Substituted Tetrahydroisoquinolines
    Jin, Dun-Yuan
    Lin, Chia-Wei
    Santhanam, Srinath
    Lin, Po-Chiao
    JOURNAL OF ORGANIC CHEMISTRY, 2024, 89 (07): : 4503 - 4511
  • [46] Intermolecular carbenoid insertions: Reactions of 2-substituted thiophenes with ethyl diazoacetate in the presence of rhodium (II) acetate.
    Tranmer, GK
    Capretta, A
    TETRAHEDRON, 1998, 54 (51) : 15499 - 15508
  • [47] Carbocation-Catalyzed Intramolecular and Intermolecular Carbonyl-Alkyne Metathesis Reactions
    Mann, Jasnoor S.
    Mai, Binh Khanh
    Nguyen, Thanh Vinh
    ACS CATALYSIS, 2023, 13 (04) : 2696 - 2701
  • [48] REACTIONS OF BENZENES WITH ACETYLENES CATALYZED BY RHODIUM CARBONYL UNDER CARBON-MONOXIDE
    HONG, P
    CHO, BR
    YAMAZAKI, H
    CHEMISTRY LETTERS, 1979, (04) : 339 - 342
  • [49] Fluorinated diazo diketones in rhodium(II)-catalyzed reactions with sultams:: Chemoselective O-functionalization of amide carbonyl groups
    Zakharova, VM
    Schulze, B
    Rodina, LL
    Sieler, J
    Nikolaev, VA
    HELVETICA CHIMICA ACTA, 2005, 88 (07) : 1913 - 1921
  • [50] Recent Applications of -Carbonyl Sulfoxonium Ylides in Rhodium- and Iridium-Catalyzed C-H Functionalizations
    Wu, Xiaopeng
    Sun, Song
    Yu, Jin-Tao
    Cheng, Jiang
    SYNLETT, 2019, 30 (01) : 21 - 29