Intermolecular rhodium(II)-catalyzed reactions with silicon-substituted carbonyl ylides

被引：15

作者：

Bolm, C ^{[1
]}

Saladin, S ^{[1
]}

Kasyan, A ^{[1
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Organ Chem, D-52056 Aachen, Germany

来源：

ORGANIC LETTERS | 2002年 / 4卷 / 26期

关键词：

D O I：

10.1021/ol026987m

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The Rh(II)-catalyzed reaction of benzyl 2-trialkylsilyi-2-diazoacetates with various acyclic and cyclic ketones affords novel dioxolanones via silicon-substituted carbonyl ylides in up to 98% yield.

引用

页码：4631 / 4633

页数：3

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