Intermolecular rhodium(II)-catalyzed reactions with silicon-substituted carbonyl ylides

被引:15
|
作者
Bolm, C [1 ]
Saladin, S [1 ]
Kasyan, A [1 ]
机构
[1] Rhein Westfal TH Aachen, Inst Organ Chem, D-52056 Aachen, Germany
关键词
D O I
10.1021/ol026987m
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The Rh(II)-catalyzed reaction of benzyl 2-trialkylsilyi-2-diazoacetates with various acyclic and cyclic ketones affords novel dioxolanones via silicon-substituted carbonyl ylides in up to 98% yield.
引用
收藏
页码:4631 / 4633
页数:3
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