The Li-Si-(O)-N system revisited: Structural characterization of Li21Si3N11 and Li7SiN3O

被引：6
|
作者：
Casas-Cabanas, M. [1 ]
Santner, H. [2 ]
Palacin, M. R. [2 ]
机构：
[1] ED CIC, CIC energiGUNE, Minano 01510, Spain
[2] CSIC, Inst Ciencia Mat Barcelona, Bellaterra 08193, Catalonia, Spain
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2014年 / 213卷
关键词：
Lithium silicon nitrides; Oxynitrides; Antifluorite structure; Crystal structure; Ionic conductors; HERSTELLUNG UND EIGENSCHAFTEN; LITHIUM BORON-NITRIDE; ELECTROCHEMICAL PROPERTIES; NEUTRON-DIFFRACTION; CRYSTAL-STRUCTURE; O-N; PHASES; OXYNITRIDE; TERNARY; COMPOUND;
D O I：
10.1016/j.jssc.2014.02.022
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A systematic study of the Li-Si-(O)-N system is presented. The synthetic conditions to prepare Li2SiN2, Li5SiN3, Li18Si3N10, Li21Si3N11 and Li7SiN3O are described and the structure of the last two compounds has been solved for the first time. While Li21Si3N11 crystallizes as a superstructure of the anti-fluorite structure with Li and Si ordering, Li7SiN3O exhibits the anti-fluorite structure with both anion and cation disorder. (C) 2014 Elsevier Inc. All rights reserved.
引用
收藏
页码：152 / 157
页数：6
相关论文
共 50 条
  • [41] Li4Ca3Si2N6 and Li4Sr3Si2N6 - Quaternary Lithium Nitridosilicates with Isolated [Si2N6]10- Ions
    Pagano, Sandro
    Lupart, Saskia
    Schmiechen, Sebastian
    Schnick, Wolfgang
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2010, 636 (11): : 1907 - 1909
  • [42] Electrochemical Characterization of Li3N-Si Nanocomposite Thin Films by Pulsed Laser Deposition
    Zhou, Yong-Ning
    Wu, Xiao-Jing
    Fu, Zheng-Wen
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2009, 156 (06) : A425 - A429
  • [43] Formation and stability of β-quartz solid-solution phase in the Li-Si-Al-O-N system
    Nordmann, A
    Cheng, YB
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1997, 80 (12) : 3045 - 3053
  • [44] Structural and electrical characterization of glasses in the Li2O-CaO-B2O3 system
    Pimentel, N. B.
    Mastelaro, V. R.
    M'Peko, J-C
    Martin, S. W.
    Rojas, S. S.
    De Souza, J. E.
    JOURNAL OF NON-CRYSTALLINE SOLIDS, 2018, 499 : 272 - 277
  • [45] Exploring order-disorder structural transitions in the Li-Nb-N-O system: The new antifluorite oxynitride Li11NbN4O2
    Cabana, J.
    Casas-Cabanas, M.
    Santner, H. J.
    Fuertes, A.
    Palacin, M. R.
    JOURNAL OF SOLID STATE CHEMISTRY, 2010, 183 (07) : 1609 - 1614
  • [46] Electrical conductivity in Li-Si-P-O-N oxynitride thin-films
    Lee, SJ
    Bae, JH
    Lee, HW
    Baik, HK
    Lee, SM
    JOURNAL OF POWER SOURCES, 2003, 123 (01) : 61 - 64
  • [47] DIELECTRIC LOSS OF Si2N2O AND THE INFLUENCE OF Li ON ITS PROPERTIES
    Yang, Yong
    He, Ming
    Zhang, Ting
    Wu, Meng-qiang
    MATERIALI IN TEHNOLOGIJE, 2022, 56 (01): : 79 - 84
  • [48] Thermodynamic destabilization of Li-N-H system by Si addition
    Palade, P.
    Lungu, G. A.
    Husanu, A. M.
    JOURNAL OF ALLOYS AND COMPOUNDS, 2010, 505 (01) : 343 - 347
  • [49] Microstructure and properties of spodumene based Li-Si-Al-O-N glass ceramics
    Nordmann, A
    Cheng, YB
    BRITISH CERAMIC TRANSACTIONS, 1997, 96 (04): : 141 - 148
  • [50] Li-Al-Si-O-N玻璃晶化成核的研究
    徐晓杰
    李家治
    姚鹿苹
    上海建材学院学报, 1989, (02) : 104 - 109
12345