The Li-Si-(O)-N system revisited: Structural characterization of Li21Si3N11 and Li7SiN3O

被引：6
|
作者：
Casas-Cabanas, M. [1 ]
Santner, H. [2 ]
Palacin, M. R. [2 ]
机构：
[1] ED CIC, CIC energiGUNE, Minano 01510, Spain
[2] CSIC, Inst Ciencia Mat Barcelona, Bellaterra 08193, Catalonia, Spain
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2014年 / 213卷
关键词：
Lithium silicon nitrides; Oxynitrides; Antifluorite structure; Crystal structure; Ionic conductors; HERSTELLUNG UND EIGENSCHAFTEN; LITHIUM BORON-NITRIDE; ELECTROCHEMICAL PROPERTIES; NEUTRON-DIFFRACTION; CRYSTAL-STRUCTURE; O-N; PHASES; OXYNITRIDE; TERNARY; COMPOUND;
D O I：
10.1016/j.jssc.2014.02.022
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A systematic study of the Li-Si-(O)-N system is presented. The synthetic conditions to prepare Li2SiN2, Li5SiN3, Li18Si3N10, Li21Si3N11 and Li7SiN3O are described and the structure of the last two compounds has been solved for the first time. While Li21Si3N11 crystallizes as a superstructure of the anti-fluorite structure with Li and Si ordering, Li7SiN3O exhibits the anti-fluorite structure with both anion and cation disorder. (C) 2014 Elsevier Inc. All rights reserved.
引用
收藏
页码：152 / 157
页数：6
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