Synthesis, characterization and X-ray crystal structures of new ethylxanthato complexes of zinc(II) with N-donor ligands

被引：6

作者：

Ara, I ^{[1
]}

El Bahij, F

Lachkar, M

机构：

[1] Univ Zaragoza, CSIC, Inst Ciencia Mat Aragon, Dept Quim Inorgan, E-50009 Zaragoza, Spain

[2] Univ Sidi Mohamed Ben Abdellah, Fac Sci Dhar Mehraz, Dept Chim, Fes, Morocco

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2006年 / 36卷 / 05期

关键词：

Zn(II) complexes; xanthate ligands; N-donor ligands; crystal structures;

D O I：

10.1080/15533170600732569

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Zn(II) complexes of general formula [Zn(S2COEt)(2) L] [L=pyrazole (Hpz) 1; 3,5-dimethylpyrazole (Hdmpz) 2; 2-pyridylamine (pyam) 3; phenyl 2-pyridylamine (phpyam) 4; 2,2'-dipyridylamine (dpyam) 5; 1,4-pyrazine (pyr) 6] have been synthesized and characterized by elemental analyses and IR and NMR spectroscopy. The crystal structures of complexes 2, 5 and 6 have been determined by X-ray diffraction, showing different geometries and modes of coordination of the xanthate ligand depending on the type of N-donor ligand.

引用

页码：399 / 406

页数：8

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