Synthesis, characterization and X-ray crystal structures of new ethylxanthato complexes of zinc(II) with N-donor ligands

被引：6
|
作者：
Ara, I [1 ]
El Bahij, F
Lachkar, M
机构：
[1] Univ Zaragoza, CSIC, Inst Ciencia Mat Aragon, Dept Quim Inorgan, E-50009 Zaragoza, Spain
[2] Univ Sidi Mohamed Ben Abdellah, Fac Sci Dhar Mehraz, Dept Chim, Fes, Morocco
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2006年 / 36卷 / 05期
关键词：
Zn(II) complexes; xanthate ligands; N-donor ligands; crystal structures;
D O I：
10.1080/15533170600732569
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Zn(II) complexes of general formula [Zn(S2COEt)(2) L] [L=pyrazole (Hpz) 1; 3,5-dimethylpyrazole (Hdmpz) 2; 2-pyridylamine (pyam) 3; phenyl 2-pyridylamine (phpyam) 4; 2,2'-dipyridylamine (dpyam) 5; 1,4-pyrazine (pyr) 6] have been synthesized and characterized by elemental analyses and IR and NMR spectroscopy. The crystal structures of complexes 2, 5 and 6 have been determined by X-ray diffraction, showing different geometries and modes of coordination of the xanthate ligand depending on the type of N-donor ligand.
引用
收藏
页码：399 / 406
页数：8
相关论文
共 50 条
  • [21] Synthesis, structural characterization, fluorescence properties and antimicrobial activities of dinuclear zinc(II) methacrylate complexes with N-donor ligands
    Yolcu, Zuhal
    Citlakog, Meryem
    JOURNAL OF MOLECULAR STRUCTURE, 2023, 1293
  • [22] Synthesis, characterization, and catalytic properties of some new ruthenium(II)/(III) complexes containing N, N-donor ligands
    Shoair, Abdel Ghany F.
    Mohamed, Ramadan H.
    JOURNAL OF COORDINATION CHEMISTRY, 2007, 60 (12) : 1279 - 1289
  • [23] Heteroleptic Zinc Catecholate Complexes with N-Donor Ligands
    A. V. Maleeva
    O. Yu. Trofimova
    I. A. Yakushev
    R. R. Aysin
    A. V. Piskunov
    Russian Journal of Coordination Chemistry, 2023, 49 : 420 - 428
  • [24] Heteroleptic Zinc Catecholate Complexes with N-Donor Ligands
    Maleeva, A. V.
    Trofimova, O. Yu.
    Yakushev, I. A.
    Aysin, R. R.
    Piskunov, A. V.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2023, 49 (07) : 420 - 428
  • [25] Synthesis, Characterization and Single Crystal X-Ray Structures of Trifluroacetylacetonate Copper(II) Complexes
    Neha Kumari
    Vir Bahadur
    Raymond J. Butcher
    Anupa A. Kumbhar
    Journal of Chemical Crystallography, 2022, 52 : 525 - 533
  • [26] Synthesis, Characterization and Single Crystal X-Ray Structures of Trifluroacetylacetonate Copper(II) Complexes
    Kumari, Neha
    Bahadur, Vir
    Butcher, Raymond J.
    Kumbhar, Anupa A.
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2022, 52 (04) : 525 - 533
  • [27] Synthesis, single crystal X-ray, DFT and HSA of N-donor stabilized complexes of cobalt(II) diphenyldithiophosphate: An experimental and theoretical approach
    Sharma, Deepika
    Radha, Anu
    Kumar, Sandeep
    Jassal, Amanpreet K.
    Rani, Namrata
    Vikas
    Pandey, Sushil K.
    JOURNAL OF MOLECULAR STRUCTURE, 2020, 1207
  • [28] Synthesis and X-ray Crystal Structures of Multinuclear Zinc Amidinate Complexes
    Schmidt, Sarah
    Gutschank, Benjamin
    Schulz, Stephan
    Blaeser, Dieter
    Boese, Roland
    Woelper, Christoph
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2011, (28) : 4464 - 4470
  • [29] Synthesis and X-ray crystal structures of heteroleptic zinc amidinate complexes
    Schmidt, Sarah
    Schulz, Stephan
    Blaeser, Dieter
    Woelper, Christoph
    MAIN GROUP METAL CHEMISTRY, 2012, 35 (1-2): : 35 - 40
  • [30] Synthesis and X-ray Crystal Structures of Homotrimetallic Zinc Bisureate Complexes
    Bayram, Melike
    Woelper, Christoph
    Schulz, Stephan
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2018, 644 (02): : 114 - 120
12345