Synthesis, characterization and X-ray crystal structures of new ethylxanthato complexes of zinc(II) with N-donor ligands

被引：6
|
作者：
Ara, I [1 ]
El Bahij, F
Lachkar, M
机构：
[1] Univ Zaragoza, CSIC, Inst Ciencia Mat Aragon, Dept Quim Inorgan, E-50009 Zaragoza, Spain
[2] Univ Sidi Mohamed Ben Abdellah, Fac Sci Dhar Mehraz, Dept Chim, Fes, Morocco
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2006年 / 36卷 / 05期
关键词：
Zn(II) complexes; xanthate ligands; N-donor ligands; crystal structures;
D O I：
10.1080/15533170600732569
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Zn(II) complexes of general formula [Zn(S2COEt)(2) L] [L=pyrazole (Hpz) 1; 3,5-dimethylpyrazole (Hdmpz) 2; 2-pyridylamine (pyam) 3; phenyl 2-pyridylamine (phpyam) 4; 2,2'-dipyridylamine (dpyam) 5; 1,4-pyrazine (pyr) 6] have been synthesized and characterized by elemental analyses and IR and NMR spectroscopy. The crystal structures of complexes 2, 5 and 6 have been determined by X-ray diffraction, showing different geometries and modes of coordination of the xanthate ligand depending on the type of N-donor ligand.
引用
收藏
页码：399 / 406
页数：8
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