Hydrogen atom in a spherical cavity: Degeneracy of energy levels and boundary conditions

被引：0

作者：

Shcherbinin, AV ^{[1
]}

Pupyshev, VI ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Fac Chem, Moscow 119899, Russia

来源：

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY | 2000年 / 74卷 / 02期

关键词：

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The Lent vector formalism was used to consider the problem of a hydrogen atom in a spherical cavity of radius R. The nature of the cavity boundary is determined by the condition f'(R) - pf(R) = 0, where p is a real parameter imposed on the radial wave function. The possibility of accidental energy level degeneracy is studied, and a comparison with similar results obtained for the impermeable cavity model is given.

引用

页码：292 / 295

页数：4

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