Hydrogen atom in a spherical cavity: Degeneracy of energy levels and boundary conditions

被引：0
|
作者：
Shcherbinin, AV [1 ]
Pupyshev, VI [1 ]
机构：
[1] Moscow MV Lomonosov State Univ, Fac Chem, Moscow 119899, Russia
来源：
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY | 2000年 / 74卷 / 02期
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D O I：
暂无
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The Lent vector formalism was used to consider the problem of a hydrogen atom in a spherical cavity of radius R. The nature of the cavity boundary is determined by the condition f'(R) - pf(R) = 0, where p is a real parameter imposed on the radial wave function. The possibility of accidental energy level degeneracy is studied, and a comparison with similar results obtained for the impermeable cavity model is given.
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页码：292 / 295
页数：4
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