Efficient and eco-compatible transition metal-free Oppenauer-type oxidation of alcohols

被引：20
|
作者：
Ballester, Jorge [1 ]
Caminade, Anne-Marie [2 ,3 ]
Majoral, Jean-Pierre [2 ,3 ]
Taillefer, Marc [1 ]
Ouali, Armelle [2 ,3 ]
机构：
[1] ENSCM, CNRS, UMR 5253, ICG,AM2N, F-34296 Montpellier 5, France
[2] CNRS, UPR 8241, Lab Chim Coordinat, F-31077 Toulouse 04, France
[3] Univ Toulouse, UPS, INPT, LCC, F-31077 Toulouse, France
来源：
CATALYSIS COMMUNICATIONS | 2014年 / 47卷
关键词：
Alcohol; Oxidation; Oppenauer; Sodium tert-butoxide; Ketone; Catalysis; MEERWEIN-PONNDORF-VERLEY; SECONDARY ALCOHOLS; TRANSFER HYDROGENATION; AEROBIC OXIDATION; REDUCTION; KETONES; DEHYDROGENATION; CATALYSTS; LIGAND;
D O I：
10.1016/j.catcom.2013.12.030
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Catalytic amounts of cheap, non-toxic, easy-to-handle and non-sensitive sodium tert-butoxide are able to promote the dehydrogenative oxidation of a wide array of secondary alcohols using inexpensive benzophenone as the H-acceptor. The corresponding ketones, highly important intermediates and targets throughout life and material sciences, are very selectively obtained under mild conditions. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：58 / 62
页数：5
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