Metal-Free Chemoselective Oxidative Dehomologation or Direct Oxidation of Alcohols: Implication for Biomass Conversion

被引：34

作者：

Kim, Sun Min ^{[1
]}

Shin, Hun Yi ^{[1
]}

Kim, Dong Wan ^{[1
]}

Yang, Jung Woon ^{[1
]}

机构：

[1] Sungkyunkwan Univ, Dept Energy Sci, 2066 Seobu Ro, Suwon 440746, Gyeonggi Do, South Korea

来源：

CHEMSUSCHEM | 2016年 / 9卷 / 03期

关键词：

biomass conversion; chemoselectivity; dehomologation; lignin; oxidation; C-C BOND; CARBON-CARBON BONDS; LIGNIN MODEL COMPOUNDS; MOLECULAR-OXYGEN; TRIPLE BOND; CATALYZED CLEAVAGE; AEROBIC OXIDATION; KETONES; ACID; DERIVATIVES;

D O I：

10.1002/cssc.201501359

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A transition metal-free, chemoselective reaction was performed using the sodium tert-butoxide-oxygen ((NaOBu)-Bu-t-O-2) system, resulting in either oxidative dehomologation or direct oxidation of alcohols. In particular, the newly developed protocol may be used to predict the major product formed, which depends on alkyl chain length of the alcohols and reaction conditions. The rational mechanism of this transformation was also demonstrated by performing an O-18 isotopic labelling experiment. This protocol presents a straightforward method for biomass conversion of a lignin model compound to phenol and benzoic acid.

引用

页码：241 / 245

页数：5

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