Efficient and eco-compatible transition metal-free Oppenauer-type oxidation of alcohols

被引：20

作者：

Ballester, Jorge ^{[1
]}

Caminade, Anne-Marie ^{[2
,3
]}

Majoral, Jean-Pierre ^{[2
,3
]}

Taillefer, Marc ^{[1
]}

Ouali, Armelle ^{[2
,3
]}

机构：

[1] ENSCM, CNRS, UMR 5253, ICG,AM2N, F-34296 Montpellier 5, France

[2] CNRS, UPR 8241, Lab Chim Coordinat, F-31077 Toulouse 04, France

[3] Univ Toulouse, UPS, INPT, LCC, F-31077 Toulouse, France

来源：

CATALYSIS COMMUNICATIONS | 2014年 / 47卷

关键词：

Alcohol; Oxidation; Oppenauer; Sodium tert-butoxide; Ketone; Catalysis; MEERWEIN-PONNDORF-VERLEY; SECONDARY ALCOHOLS; TRANSFER HYDROGENATION; AEROBIC OXIDATION; REDUCTION; KETONES; DEHYDROGENATION; CATALYSTS; LIGAND;

D O I：

10.1016/j.catcom.2013.12.030

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Catalytic amounts of cheap, non-toxic, easy-to-handle and non-sensitive sodium tert-butoxide are able to promote the dehydrogenative oxidation of a wide array of secondary alcohols using inexpensive benzophenone as the H-acceptor. The corresponding ketones, highly important intermediates and targets throughout life and material sciences, are very selectively obtained under mild conditions. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：58 / 62

页数：5

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