Protonation of bridged acetate anion in the {(H2O)Zn(μ,η2-OOCMe)[η5-C5H4(COO)]Mn(CO)3} n-3,5-dimethylpyrazole polymer yields binuclear pyrazolate-bridged complex

被引：5

作者：

Uvarova, M. A. ^{[1
]}

Ageshina, A. A. ^{[1
]}

Grineva, A. A. ^{[2
]}

Vitukhnovskii, A. G. ^{[3
]}

Nefedov, S. E. ^{[1
]}

机构：

[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

[2] Voronezh State Univ, Voronezh 394693, Russia

[3] Russian Acad Sci, Lebedev Phys Inst, Moscow, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2015年 / 60卷 / 05期

基金：

俄罗斯基础研究基金会;

关键词：

Pyrazolate; Zinc Acetate; Binuclear Complex; Pivalate; Cymantrene;

D O I：

10.1134/S0036023615050186

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction between aqueous zinc acetate and two moles of cymantrene carboxylic acid under mild conditions is found to give rise to {(H2O)Zn(mu,eta(2)-OOCMe)[eta(5)-C5H4(COO)]Mn(CO)(3) polymer, whose reaction with 3,5-dimethylpyrazole yields binuclear pyrazolate-bridged complex Zn-2(mu-dmpz)(2)(Hdmpz)(2)[eta(5)-C5H4(COO)]Mn(CO)(3)](2). The structure of the resulting complexes was identified by X-ray diffraction.

引用

页码：566 / 571

页数：6

共 50 条

[41] Amine attack on the carbonyl ligands of the protonated dicyclopentadienyl-bridged diruthenium complex [{(η5-C5H3)2(SiMe2)2}Ru2(CO)4(μ-H)]+
Ovchinnikov, MV
Guzei, IA
Angelici, RJ
ORGANOMETALLICS, 2001, 20 (04) : 691 - 696
[42] SYNTHESES AND SPECTRA OF (CO)(2)(NO)CR(ETA(5)-C5H4-R) (R=-C(O)-N-3,-N=C=O,-NH2,-NH-C(O)-O-CH2C6H5 OR -NH-C(O)-NH-(ETA(5)-C5H4)CR(CO)(2)(NO)) AND CRYSTAL-STRUCTURE OF (CO)(2)(NO)CR[(ETA(5)-C5H4)-NH-C(O)-NH-(ETA(5)-C5H4)]CR(CO)(2)(NO)
WANG, YP
LIN, TS
YANG, YH
LIAW, JH
WANG, SL
LIAO, FL
LU, YJ
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 503 (01) : 35 - 45
[43] Synthesis and crystal structure of an azide bridged binuclear zinc(II) dimer containing taurine Schiff base [Zn2(C8H9N2O3S)2•(N3)2•(H2O)2]2•2H2O
Jiang Yi-Min
Li Jia-Ming
Xie Fu-Qing
Wang Yan-Fei
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2006, 25 (07) : 767 - 770
[44] Synthesis, crystal structure and properties of trinuclear manganese complex [Mn3O(O2CC6H5)6(C3H4N2)3] C6H5CO2•0.5H2O
Li, J
Zhang, FX
Tang, ZX
Shi, QZ
ACTA CHIMICA SINICA, 2001, 59 (07) : 1116 - 1120
[45] Crystal structure of hexakis(μ2-chloro)-μ4-oxo-tetrakis((3,5-dimethylpyrazole)copper(II)) ethanol tetrasolvate,Cu4OCl6(C5H8N2)4•4C2H5OH
Jacimovic, Zeljko K.
Leovac, Vukadin M.
Tomic, Zoran D.
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2007, 222 (03): : 246 - 248
[46] Synthesis and crystal structure of oxalato-bridged binuclear copper(II) complex [Cu2(phen)2(H2O)2(μ2-C2O4)](NO3)2
Lu, WG
Pan, YF
Peng, CH
CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2005, 21 (05) : 709 - 712
[47] Layered metal phosphonates containing pyridyl groups:: Syntheses and characterization of Mn2(2-C5H4NPO3)2(H2O) and Zn(6-Me-2-C5H4NPO3)
Ma, Yun-Sheng
Yang, Yi-Fan
Gao, Song
Li, Yi-Zhi
Zheng, Li-Min
JOURNAL OF SOLID STATE CHEMISTRY, 2006, 179 (10) : 3017 - 3023
[48] [MN6O2(O2C-3,5-(NO2)(2)-C6H3)(10)-(C5H5N)(2)((CH3)(2)CO)(2)]CENTER-DOT-2(CH3)(2)CO-CENTER-DOT-2(C2H5)(2)O AND [MN6O2(O2CC6H5)(10)-(NCCH3)(4)]
HALCROW, MA
STREIB, WE
FOLTING, K
CHRISTOU, G
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1995, 51 : 1263 - 1267
[49] PHOTOCHEMICAL HYDROGENOLYSIS OF THE PHOSPHORUS-CYCLOPENTADIENYL BOND OF (CO)4MNMO(CO)3[ETA-5-C5H4P(C6H4-P-CH3)2] AND FORMATION OF THE PHOSPHIDO-BRIDGED METAL HYDRIDE COMPLEX (CO)4MN[MU-P(C6H4-PARA-CH3)2](MU-H)MO(CO)2(C5H5)
CASEY, CP
BULLOCK, RM
ORGANOMETALLICS, 1984, 3 (07) : 1100 - 1104
[50] Squarate and croconate in designing one-and two-dimensional oxamidato-bridged copper(II) complexes:: synthesis, crystal structures and magnetic properties of [Cu2(apox)(C4O4)(H2O)2]n•n H2O and [Cu4(apox)2(C5O5)2]•6 H2O
Castro, I
Calatayud, ML
Sletten, J
Julve, M
Lloret, F
COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE C-CHIMIE, 2001, 4 (03): : 235 - 243

← 1 2 3 4 5 →