Protonation of bridged acetate anion in the {(H2O)Zn(μ,η2-OOCMe)[η5-C5H4(COO)]Mn(CO)3} n-3,5-dimethylpyrazole polymer yields binuclear pyrazolate-bridged complex

被引：5
|
作者：
Uvarova, M. A. [1 ]
Ageshina, A. A. [1 ]
Grineva, A. A. [2 ]
Vitukhnovskii, A. G. [3 ]
Nefedov, S. E. [1 ]
机构：
[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia
[2] Voronezh State Univ, Voronezh 394693, Russia
[3] Russian Acad Sci, Lebedev Phys Inst, Moscow, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2015年 / 60卷 / 05期
基金：
俄罗斯基础研究基金会;
关键词：
Pyrazolate; Zinc Acetate; Binuclear Complex; Pivalate; Cymantrene;
D O I：
10.1134/S0036023615050186
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction between aqueous zinc acetate and two moles of cymantrene carboxylic acid under mild conditions is found to give rise to {(H2O)Zn(mu,eta(2)-OOCMe)[eta(5)-C5H4(COO)]Mn(CO)(3) polymer, whose reaction with 3,5-dimethylpyrazole yields binuclear pyrazolate-bridged complex Zn-2(mu-dmpz)(2)(Hdmpz)(2)[eta(5)-C5H4(COO)]Mn(CO)(3)](2). The structure of the resulting complexes was identified by X-ray diffraction.
引用
收藏
页码：566 / 571
页数：6
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