Protonation of bridged acetate anion in the {(H2O)Zn(μ,η2-OOCMe)[η5-C5H4(COO)]Mn(CO)3} n-3,5-dimethylpyrazole polymer yields binuclear pyrazolate-bridged complex

被引：5

作者：

Uvarova, M. A. ^{[1
]}

Ageshina, A. A. ^{[1
]}

Grineva, A. A. ^{[2
]}

Vitukhnovskii, A. G. ^{[3
]}

Nefedov, S. E. ^{[1
]}

机构：

[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

[2] Voronezh State Univ, Voronezh 394693, Russia

[3] Russian Acad Sci, Lebedev Phys Inst, Moscow, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2015年 / 60卷 / 05期

基金：

俄罗斯基础研究基金会;

关键词：

Pyrazolate; Zinc Acetate; Binuclear Complex; Pivalate; Cymantrene;

D O I：

10.1134/S0036023615050186

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction between aqueous zinc acetate and two moles of cymantrene carboxylic acid under mild conditions is found to give rise to {(H2O)Zn(mu,eta(2)-OOCMe)[eta(5)-C5H4(COO)]Mn(CO)(3) polymer, whose reaction with 3,5-dimethylpyrazole yields binuclear pyrazolate-bridged complex Zn-2(mu-dmpz)(2)(Hdmpz)(2)[eta(5)-C5H4(COO)]Mn(CO)(3)](2). The structure of the resulting complexes was identified by X-ray diffraction.

引用

页码：566 / 571

页数：6

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