Diaqua[N, N′-bis(salicylidene) propanediamine(2-)] manganese(III) chloride

被引：2

作者：

Hwang, In-Chul

Ha, Kwang ^{[1
]}

机构：

[1] Chonnam Natl Univ, Res Inst Catalysis, Sch Appl Chem Engn, Kwangju 500757, South Korea

[2] Pohang Univ Sci & Technol, Dept Chem, Pohang 790784, South Korea

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷

关键词：

D O I：

10.1107/S1600536807039475

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound (systematic name: diaqua{2,2 '-[propane1,3-diylbis(nitrilomethylidyne)]diphenolato} manganese(III) chloride), [Mn(C17H16N2O2)(H2O)(2)]Cl, consists of an Mn III cation complex and a counter-anion. In the complex, the Mn3+ ion is six-coordinated by the dianion of the tetradentate ligand N,N '-bis(salicylidene)-1,3-diaminopropane and two water molecules in a distorted octahedral geometry. The molecules are assembled through intermolecular O-H center dot center dot center dot Cl and O - H center dot center dot center dot O hydrogen bonds and pi - pi interactions [ the centroid centroid distance is 3.865 angstrom and the dihedral angle between the ring planes is 12.9 degrees] along the a axis.

引用

页码：M2337 / U831

页数：11

共 50 条

[41] MASS-SPECTROMETRIC STUDY OF POLYDENTATE SCHIFF-BASE COORDINATION-COMPLEXES .2. COBALT(II), NICKEL(II), AND COPPER(II) COMPLEXES OF N,N'-BIS(SALICYLIDENE)HEPTANEDIAMINE, N,N'-BIS(SALICYLIDENE)-3,3'-BIS(AMINOPROPYL)AMINE, N,N'-BIS(SALICYLIDENE)3,3'-BIS(AMINOPROPYL) ETHER, AND N,N'-BIS(SALICYLIDENE)-3,3'-BIS(AMINOPROPYL) SULFIDE
TAYLOR, LT
DILLARD, JG
INORGANIC CHEMISTRY, 1974, 13 (11) : 2620 - 2630
[42] Diaqua[N,N′-bis(3-carboxyprop-2-enoyl)pyridine-2,6-dicarbohydrazidato(2-)]cadmium(II) N,N-dimethylformamide disolvate
Cao, Quanfu
Li, Dacheng
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M464 - U1092
[43] STRUCTURE OF N,N'-ETHYLENEBIS(SALICYLIDENEIMINATO)MANGANESE(III) CHLORIDE ACETONITRILE SOLVATE
PECORARO, VL
BUTLER, WM
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1986, 42 : 1151 - 1154
[44] N,N′-bis(salicylidene)-1-4-butanediamine
Kennedy, AR
Reglinski, J
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2001, 57 : O1027 - O1028
[45] PREPARATIONS AND PARTIAL STRUCTURAL ASSIGNMENTS OF OCTAHEDRAL N,N'-BIS(2-PYRIDYLMETHYL)-1,2(R)-PROPANEDIAMINE COMPLEXES OF COBALT(III) AND CHROMIUM(III)
MICHELSEN, K
NIELSEN, KM
ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1980, 34 (10): : 755 - 764
[46] THE STRUCTURE OF DIAQUA(N-SALICYLIDENE-L-THREONINATO)COPPER(II)
KORHONEN, K
HAMALAINEN, R
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1981, 37 (APR): : 829 - 834
[47] Cyclization of N,N′ bis(salicylidene)diamines with carbon suboxide
Chimenti, F
Secci, D
Bolasco, A
Chimenti, P
Granese, A
SYNTHETIC COMMUNICATIONS, 2005, 35 (06) : 769 - 773
[48] N,N′-bis(5-bromo-2-hydroxybenzylidene)-1,3-propanediamine
Elerman, Y
Elmali, A
Kabak, M
Svoboda, I
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1998, 54 : 1701 - 1703
[49] Bis(μ-N,N-dimethylhydrazido-κ2N′:N′)bis[dimethylgallium(III)]
Hecht, E
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2004, 60 : M1327 - M1328
[50] [N,N′-Bis(salicylidene)-2,2-dimethyl-1,3-propanediaminato]nickel(II) and [N,N′-bis(salicylidene)-2,2-dimethyl-1,3-propanediaminato]copper(II)
Arici, C
Ercan, F
Kurtaran, R
Atakol, O
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2001, 57 (57) : 812 - 814

← 1 2 3 4 5 →