Diaqua[N, N′-bis(salicylidene) propanediamine(2-)] manganese(III) chloride

被引：2
|
作者：
Hwang, In-Chul
Ha, Kwang [1 ]
机构：
[1] Chonnam Natl Univ, Res Inst Catalysis, Sch Appl Chem Engn, Kwangju 500757, South Korea
[2] Pohang Univ Sci & Technol, Dept Chem, Pohang 790784, South Korea
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷
关键词：
D O I：
10.1107/S1600536807039475
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound (systematic name: diaqua{2,2 '-[propane1,3-diylbis(nitrilomethylidyne)]diphenolato} manganese(III) chloride), [Mn(C17H16N2O2)(H2O)(2)]Cl, consists of an Mn III cation complex and a counter-anion. In the complex, the Mn3+ ion is six-coordinated by the dianion of the tetradentate ligand N,N '-bis(salicylidene)-1,3-diaminopropane and two water molecules in a distorted octahedral geometry. The molecules are assembled through intermolecular O-H center dot center dot center dot Cl and O - H center dot center dot center dot O hydrogen bonds and pi - pi interactions [ the centroid centroid distance is 3.865 angstrom and the dihedral angle between the ring planes is 12.9 degrees] along the a axis.
引用
收藏
页码：M2337 / U831
页数：11
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