Diaqua[N, N′-bis(salicylidene) propanediamine(2-)] manganese(III) chloride

被引：2

作者：

Hwang, In-Chul

Ha, Kwang ^{[1
]}

机构：

[1] Chonnam Natl Univ, Res Inst Catalysis, Sch Appl Chem Engn, Kwangju 500757, South Korea

[2] Pohang Univ Sci & Technol, Dept Chem, Pohang 790784, South Korea

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷

关键词：

D O I：

10.1107/S1600536807039475

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound (systematic name: diaqua{2,2 '-[propane1,3-diylbis(nitrilomethylidyne)]diphenolato} manganese(III) chloride), [Mn(C17H16N2O2)(H2O)(2)]Cl, consists of an Mn III cation complex and a counter-anion. In the complex, the Mn3+ ion is six-coordinated by the dianion of the tetradentate ligand N,N '-bis(salicylidene)-1,3-diaminopropane and two water molecules in a distorted octahedral geometry. The molecules are assembled through intermolecular O-H center dot center dot center dot Cl and O - H center dot center dot center dot O hydrogen bonds and pi - pi interactions [ the centroid centroid distance is 3.865 angstrom and the dihedral angle between the ring planes is 12.9 degrees] along the a axis.

引用

页码：M2337 / U831

页数：11

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