Bis(1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane) persulfate: A mild and efficient oxidant for cleavage of oxime double bonds under anhydrous conditions

被引：0

作者：

Hajipour, R ^{[1
]}

Mohammadpoor-Baltork, I

Kianfar, G

机构：

[1] Isfahan Univ Technol, Coll Chem, Esfahan, Iran

[2] Isfahan Univ, Dept Chem, Esfahan, Iran

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY | 1999年 / 38卷 / 02期

关键词：

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Bis(1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane)persulfate (BAABCPS) 1 readily prepared as orange solid from commercially available 1,4-diazabicyclo[2.2.2]octane (DABCO) and potassium persulfate, converts oximes and alpha-sulfinyl oximes to the corresponding carbonyl compounds and beta-keto sulfoxides respectively, the yields and enantiomeric purity are excellent.

引用

页码：221 / 224

页数：4

共 38 条

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