Bis(1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane) persulfate: A mild and efficient oxidant for cleavage of oxime double bonds under anhydrous conditions

被引：0

作者：

Hajipour, R ^{[1
]}

Mohammadpoor-Baltork, I

Kianfar, G

机构：

[1] Isfahan Univ Technol, Coll Chem, Esfahan, Iran

[2] Isfahan Univ, Dept Chem, Esfahan, Iran

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY | 1999年 / 38卷 / 02期

关键词：

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Bis(1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane)persulfate (BAABCPS) 1 readily prepared as orange solid from commercially available 1,4-diazabicyclo[2.2.2]octane (DABCO) and potassium persulfate, converts oximes and alpha-sulfinyl oximes to the corresponding carbonyl compounds and beta-keto sulfoxides respectively, the yields and enantiomeric purity are excellent.

引用

页码：221 / 224

页数：4

共 38 条

[11] Facile deprotection of trimethylsilyl ethers with modified, borohydride agents; 1-Benzyl-4-aza-1-azoniabicyclo[2.2.2]octane tetrahydroborate (BAAOTB) versus tetrabutylammonium tetrahydroborate(TBATB).
Firouzabadi, H
Afsharifar, GR
SYNTHETIC COMMUNICATIONS, 1996, 26 (06) : 1065 - 1073
[12] Facile deprotection of trimethylsilyl ethers with modified borohydride agents; 1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane tetrahydroborate (BAAOTB)1 versus tetrabutylammonium tetrahydroborate(TBATB)
Chemistry Department, Shiraz University, Shiraz 71454, Iran
Synth. Commun., 6 (1065-1073):
[13] Oxidation of alcohols with 1-decyl-4-aza-1-azoniabicyclo[2.2.2]-octane chlorochromate under conventional and solvent-free conditions
Hajipour, A. R.
Bagheri, H. R.
Ruoho, A. E.
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2006, 42 (06) : 844 - 848
[14] Oxidation of alcohols with 1-butyl-4-aza-1-azoniabicyclo[2.2.2] octane chlorochromate (BAAOCC) under non-aqueous conditions
Hajipour, AR
Bagheri, HR
Ruoho, AE
INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 2005, 44 (03): : 577 - 580
[15] Oxidation of thiols with 1-butyl-4-aza-1-azoniabicyclo[2.2.2]octane dichromate (BABOD) under non-aqueous conditions
Hajipour, AR
Bagheri, H
Ruoho, AE
JOURNAL OF CHEMICAL RESEARCH, 2004, (04) : 286 - 287
[16] (BeDABCO)2Pd2Cl6 (1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane chloride) as a highly active catalytic system for the Stille cross-coupling reaction under microwave irradiation
Hajipour, Abdol R.
Najafi, Narges
Rafiee, Fatemeh
APPLIED ORGANOMETALLIC CHEMISTRY, 2013, 27 (04) : 228 - 231
[17] 1-butyl-4-aza-1-azoniabicyclo[2.2.2]octane dichromate (BAAOD): An efficient and novel reagent for oxidation of sulfides to the corresponding sulfoxides
Hajipour, AR
Bagheri, HR
Ruoho, AE
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2003, 178 (11) : 2441 - 2446
[18] Copper(I)-mediated quaternisation of 1,4-diazabicyclo[2.2.2]octane (DABCO).: Crystal structure of bis{(1-chloromethyl-4-aza-1-azoniabicyclo[2.2.2]octane)-μ-chloro-chlorocopper(I)}
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INORGANICA CHIMICA ACTA, 2005, 358 (04) : 1309 - 1312
[19] Crystal structure of di-mu(2)-chlorido-bis[(1-aza-4-azoniabicyclo[2.2.2]octane-kappa N-1)-dichloridodicadmium]
Yan, Jing-Jing
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ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : M259 - U387
[20] Solvation structure and dynamics of Li+ in Lewis-basic ionic liquid of 1-octy1-4-aza-l-azoniabicyclo[2.2.2]octane bis(trifluoromethanesulfonyl)amide
Umecky, Tatsuya
Suga, Kenta
Masaki, Eiji
Takamuku, Toshiyuki
Makino, Takashi
Kanakubo, Mitsuhiro
JOURNAL OF MOLECULAR LIQUIDS, 2015, 209 : 557 - 562

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